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Merck
CN

197378

Sigma-Aldrich

苦味酸

moistened with water, ≥98%

别名:

2,4,6-三硝基苯酚, PA

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About This Item

线性分子式:
(O2N)3C6H2OH
CAS号:
分子量:
229.10
颜色索引号:
10305
Beilstein:
423400
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:

蒸汽密度

7.9 (vs air)

质量水平

蒸汽压

1 mmHg ( 195 °C)

检测方案

≥98%

形式

powder or crystals (with a top layer of Liquid)

包含

≥35% water

expl. lim.

0.01 %

mp

122-123 °C (dried material) (lit.)

溶解性

alcohol: 1 (g/12 mL)(lit.)
benzene: 1 g/10 mL
chloroform: 1 (g/35 mL)
diethyl ether: 1 (g/65 mL)

密度

1.763 g/cm3

SMILES字符串

Oc1c(cc(cc1[N+]([O-])=O)[N+]([O-])=O)[N+]([O-])=O

InChI

1S/C6H3N3O7/c10-6-4(8(13)14)1-3(7(11)12)2-5(6)9(15)16/h1-2,10H

InChI key

OXNIZHLAWKMVMX-UHFFFAOYSA-N

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一般描述

苦味酸(PA,2,4,6-三硝基苯酚)是一种多硝基芳香酸它本质上具有强酸性。由于它易溶于水,因此很容易污染环境。研究人员已经报道过通过三咪唑盐、荧光 [3+2] 自组装纳米级有机笼和罗丹明传感器对 PA 进行灵敏检测。它广泛用于分光光度法和萃取分光光度法测定各种有机化合物。

应用

苦味酸可用于比索洛尔的定量测定
苦味酸已用于制备 Bouin′ 固定液和苦味酸/叠氮化钠/多壁碳纳米管。

象形图

FlameSkull and crossbones

警示用语:

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Desen. Expl. 1

WGK

WGK 2

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

法规信息

监管及禁止进口产品

分析证书(COA)

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Bijan Roy et al.
The Journal of organic chemistry, 78(3), 1306-1310 (2013-01-12)
Two new anthracene-functionalized fluorescent tris-imidazolium salts have been synthesized, characterized, and proven to be selective sensors for picric acid, which is a common constituent of many powerful explosives. Theoretical studies revealed an unusual ground-state electron transfer from picrate anion to
Mario Sanhueza et al.
Journal of visualized experiments : JoVE, (111)(111), doi:10-doi:10 (2016-05-24)
Most studies on morphogenesis rely on qualitative descriptions of how anatomical traits are affected by the disruption of specific genes and genetic pathways. Quantitative descriptions are rarely performed, although genetic manipulations produce a range of phenotypic effects and variations are
Preparation and evaluation of hybrid composites of chemical fuel and multi-walled carbon nanotubes in the study of thermopower waves.
Hwang H, et al.
Journal of Visualized Experiments, 98, e52818- e52818 (2015)
Koushik Acharyya et al.
Chemical communications (Cambridge, England), 50(99), 15788-15791 (2014-11-06)
Dynamic covalent imine chemistry has been utilized to synthesize a fluorescent [3+2] self-assembled nanoscopic organic cage. The fluorescent nature of the reduced analogue of the cage was further exploited for the highly selective detection of the explosive picric acid (PA).
Rhodamine based selective turn-on sensing of picric acid.
Sivaraman G, et al.
Royal Society of Chemistry Advances, 4(58), 30828-30831 (2014)

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