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Merck
CN
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文件

19671

Sigma-Aldrich

4-叔丁基儿茶酚

≥99.0%

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别名:
4-(1,1-Dimethylethyl)benzene-1,2-diol, 4-tert-Butylcatechin, 4-tert-Butylpyrocatechol, 4-TBC, p-tert-Butylcatechol
线性分子式:
(CH3)3CC6H3-1,2-(OH)2
CAS号:
98-29-3
分子量:
166.22
Beilstein:
2043335
EC 号:
202-653-9
MDL编号:
MFCD00002201
UNSPSC代码:
12352100
PubChem化学物质编号:
57647804
NACRES:
NA.22

质量水平

100

检测方案

≥99.0%

形式

powder

bp

285 °C (lit.)

mp

52-55 °C (lit.)
56-58 °C

溶解性

methanol: soluble 1 g/10 mL, clear, colorless

SMILES字符串

CC(C)(C)c1ccc(O)c(O)c1

InChI

1S/C10H14O2/c1-10(2,3)7-4-5-8(11)9(12)6-7/h4-6,11-12H,1-3H3

InChI key

XESZUVZBAMCAEJ-UHFFFAOYSA-N

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相关类别

一般描述

在酪氨酸酶的催化下，O2 存在下，4- 叔 -丁基邻苯二酚生成 4- 叔 -丁基- O -苯醌 。用循环伏安法和控制电位库仑法研究了 4--叔 -丁基邻苯二酚在 4-羟基香豆素存在下的电化学氧化。它通过阳极氧化进行电化学三聚反应，并利用循环伏安法和控制电位库仑法研究了三聚反应的机理 。

应用

  • Antioxidant source for radical reactions: Research identified 4-tert-Butylcatechol as a viable source of hydrogen atoms in radical reactions, specifically in deiodination processes, expanding its utility in synthetic organic chemistry (Povie et al., 2016).

警示用语：

Danger

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1

WGK

WGK 3

闪点(°F)

235.4 °F

闪点(°C)

113 °C

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Mechanistic study of electrochemical oxidation of 4-tert-butylcatechol: A facile electrochemical method for the synthesis of new trimer of 4-tert-butylcatechol.
Nematollahi D, et al.
Electrochimica Acta, 49(15), 2495-2502 (2004)
Electrochemical study of 3, 4-dihydroxybenzoic acid and 4-tert-butylcatechol in the presence of 4-hydroxycoumarin application to the electro-organic synthesis of coumestan derivatives.
Golabi SM and Nematollahi D.
Journal of Electroanalytical Chemistry, 430(1), 141-146 (1997)
An unusual delayed patch test reaction to para-tertiary-butylcatechol.
R C Yu et al.
Contact dermatitis, 22(2), 110-111 (1990-02-01)
Sirley V Pereira et al.
The Analyst, 136(22), 4745-4751 (2011-10-11)
In this article we report the development of an integrated microfluidic system coupled to a screen-printed carbon electrode (SPCE) applied to the quantitative determination of IgG specific antibodies present in serum samples of patients that suffer from Chagas disease. This
J N Rodríguez-López et al.
Biochimica et biophysica acta, 1548(2), 238-256 (2001-08-22)
Using gas chromatography-mass spectrometry, the direct enzymatic release of o-diphenol (4-tert-butylcatechol) during the action of tyrosinase on a monophenol (4-tert-butylphenol) has been demonstrated for the first time in the literature. The findings confirm the previously proposed mechanism to explain the
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