质量水平
检测方案
≥98%
形式
liquid
旋光性
[α]24/D −50.5°, neat
折射率
n20/D 1.461 (lit.)
bp
192-194 °C (lit.)
mp
5-6 °C (lit.)
密度
0.948 g/mL at 25 °C (lit.)
SMILES字符串
CC1(C)C2CCC(C)(C2)C1=O
InChI
1S/C10H16O/c1-9(2)7-4-5-10(3,6-7)8(9)11/h7H,4-6H2,1-3H3/t7-,10+/m0/s1
InChI key
LHXDLQBQYFFVNW-OIBJUYFYSA-N
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一般描述
(1R)-(-)-葑酮是在茴香油和金钟柏油中发现的桥连双环酮 。
应用
(1R)-(-)-葑酮与吡啶基烷基胺进行缩合形成手性亚氨基吡啶配体，这些配体可用于对映选择性铜催化的亨利（硝基羟醛）反应。它也可以用于制备对映体C（7）-抗取代的 Fenchones 作为新的手性来源。
危险声明
预防措施声明
危险分类
Aquatic Chronic 2
WGK
WGK 2
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Regio-and stereochemical course of the ring expansion of bridged bicyclic ketones to spirocyclic a-keto tetrahydrofurans.
Paquette LA, et al.
The Journal of Organic Chemistry, 57(14), 3956-3965 (1992)
Modular iminopyridine ligands. Application to the enantioselective copper (II)-catalyzed Henry reaction.
Blay G, et al.
Tetrahedron Asymmetry, 17(14), 2046-2049 (2006)
First access to enantiopure C (7)-substituted fenchones: new norbornane-based chiral materials from the chiral pool.
Marti'nez AG, et al.
Tetrahedron Asymmetry, 14(12), 1607-1609 (2003)
(1R)-(-)-Fenchone.
Bond AD and Davies JE.
Acta Crystallographica Section E, Structure Reports Online, 57(11), o1034-o1035 (2001)
Philip C Bulman Page et al.
The Journal of organic chemistry, 67(22), 7787-7796 (2002-10-26)
The first two stable enantiomerically pure chiral N-H oxaziridines, derived from camphor and fenchone, are shown to act as electrophilic sources of nitrogen upon reaction with various carbon nucleophiles. Nitrogen is transferred, together with the camphor/fenchone unit, when deprotonated esters
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