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质量水平
检测方案
98%
mp
192-194 °C (lit.)
SMILES字符串
COc1ccc(cc1[N+]([O-])=O)C(O)=O
InChI
1S/C8H7NO5/c1-14-7-3-2-5(8(10)11)4-6(7)9(12)13/h2-4H,1H3,(H,10,11)
InChI key
ANXBDAFDZSXOPQ-UHFFFAOYSA-N
应用
4-Methoxy-3-nitrobenzoic acid was used in the synthesis of:
- BIPHEP-1-OMe [BIHEP= (2,2′-bis(diphenylphosphino)biphenyl)], precatalyst for reductive coupling of butadiene to aldehydes
- aniline mustard analogues, having potential anti-tumor activity
警示用语：
Warning
危险声明
危险分类
Acute Tox. 4 Oral
WGK
WGK 1
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Jason R Zbieg et al.
Advanced synthesis & catalysis, 352(14-15), 2416-2420 (2010-12-18)
Exposure of alcohols 1a-1i to butadiene in the presence of a cyclometallated iridium catalyzed derived from allyl acetate, 4-methoxy-3-nitrobenzoic acid and BIPHEP (2,2'-bis(diphenylphosphino)biphenyl) results in hydrogen transfer to generate aldehyde-allyliridium pairs, which engage in C-C coupling to form products of
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