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Merck
CN

195731

Sigma-Aldrich

五羰基铁

greener alternative

别名:

五羰基铁, 羰基铁

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About This Item

线性分子式:
Fe(CO)5
CAS号:
分子量:
195.90
EC 号:
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22

蒸汽密度

6.74 (vs air)

质量水平

蒸汽压

35 mmHg ( 25 °C)
40 mmHg ( 30.3 °C)

自燃温度

122 °F

反应适用性

core: iron
reagent type: catalyst

环保替代产品特性

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

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折射率

n20/D 1.5196 (lit.)

bp

103 °C (lit.)

mp

−20 °C (lit.)

密度

1.49 g/mL at 25 °C (lit.)

环保替代产品分类

储存温度

2-8°C

SMILES字符串

[Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/5CO.Fe/c5*1-2;

InChI key

FYOFOKCECDGJBF-UHFFFAOYSA-N

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一般描述

我们致力为您提供更环保的替代产品,以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型,提高了催化效率。 点击此处了解更多信息。

应用

五羰基铁(0)可用于:
  • 作为铁源,用于合成铁掺杂的薄TiO2薄膜。
  • 作为合成金(I)和Fe(CO)5以及 银和Fe(CO)5配合物的配体。
用作以下过程的反应物:
  • 加成反应
  • 通过光解分解
  • 热分解法制备尺寸分布窄的铁洋葱状富勒烯磁性微粒
  • 碳酰胺氢硅烷还原反应中七核铁羰基簇合物的制备

  • 高碱性条件下制备光催化析氢 Fe 纳米粒子的前驱体

象形图

FlameSkull and crossbones

警示用语:

Danger

危险分类

Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Flam. Liq. 2

WGK

WGK 1

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

监管及禁止进口产品

分析证书(COA)

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Djordje Miljković et al.
Journal of neurochemistry, 118(2), 205-214 (2011-05-11)
Experimental autoimmune encephalomyelitis (EAE) is a model of multiple sclerosis. Dark Agouti rats immunized with spinal cord homogenate (SCH) and carbonyl iron (CI), as an adjuvant, develop severe hyperacute form of EAE. They succumb to EAE earlier and have higher
Lindsay Hewison et al.
Dalton transactions (Cambridge, England : 2003), 39(38), 8967-8975 (2010-08-18)
New CO-releasing molecules, CO-RMs, based on indenyl iron carbonyls have been identified. Half-lives for carbon monoxide (CO) release, (1)H NMR, (13)C NMR, IR, mass spectra, elemental analysis and biological data have been determined for the compounds. Limited correlations have been
Plasma enhanced chemical vapor deposition of iron doped thin dioxide films, their structure and photowetting effect.
Sobczyk-Guzenda A, et al.
Thin Solid Films, 589, 605-612 (2015)
Heterobimetallic Complexes Featuring Fe(CO)5 as a Ligand on Gold.
Wang G, et al.
Chemistry?A European Journal , 23(68), 17222-17226 (2017)
Tetsu Mitsumata et al.
The journal of physical chemistry. B, 116(40), 12341-12348 (2012-09-15)
A new class of magnetoelastic gel that demonstrates drastic and reversible changes in storage modulus without using strong magnetic fields was obtained. The magnetic gel consists of carrageenan and carbonyl iron particles. The magnetic gel with a volume fraction of

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