195731
五羰基铁
别名:
五羰基铁, 羰基铁
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关于此项目
线性分子式:
Fe(CO)5
化学文摘社编号:
分子量:
195.90
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
236-670-8
MDL number:
InChI key
FYOFOKCECDGJBF-UHFFFAOYSA-N
InChI
1S/5CO.Fe/c5*1-2;
SMILES string
[Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
vapor density
6.74 (vs air)
vapor pressure
35 mmHg ( 25 °C)
40 mmHg ( 30.3 °C)
autoignition temp.
122 °F
reaction suitability
core: iron
reagent type: catalyst
greener alternative product characteristics
Catalysis
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sustainability
Greener Alternative Product
refractive index
n20/D 1.5196 (lit.)
bp
103 °C (lit.)
mp
−20 °C (lit.)
density
1.49 g/mL at 25 °C (lit.)
greener alternative category
, Aligned
storage temp.
2-8°C
Quality Level
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Application
五羰基铁（0）可用于：
- 作为铁源，用于合成铁掺杂的薄TiO2薄膜。
- 作为合成金（I）和Fe（CO）5以及 银和Fe（CO）5配合物的配体。
用作以下过程的反应物：
- 加成反应
- 通过光解分解
- 热分解法制备尺寸分布窄的铁洋葱状富勒烯磁性微粒
- 碳酰胺氢硅烷还原反应中七核铁羰基簇合物的制备
- 高碱性条件下制备光催化析氢 Fe 纳米粒子的前驱体
General description
我们致力为您提供更环保的替代产品，以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型，提高了催化效率。 点击此处了解更多信息。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
5.0 °F - closed cup
flash_point_c
-15 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
Plasma enhanced chemical vapor deposition of iron doped thin dioxide films, their structure and photowetting effect.
Sobczyk-Guzenda A, et al.
Thin Solid Films, 589, 605-612 (2015)
Heterobimetallic Complexes Featuring Fe(CO)5 as a Ligand on Gold.
Wang G, et al.
Chemistry?A European Journal , 23(68), 17222-17226 (2017)
Heterobimetallic Silver-Iron Complexes Involving Fe(CO)5 Ligands
Wang G, et al.
Journal of the American Chemical Society, 139(40), 14292-14301 (2017)
Miguel D Ferrer et al.
The British journal of nutrition, 103(1), 69-76 (2009-11-04)
Our aim was to analyse the influence of variegate porphyria (VP) on the antioxidant defenses and markers of oxidative damage and inflammation in plasma and neutrophils and the effects of dietary supplementation with vitamins E and C on these parameters
Ioan Silaghi-Dumitrescu et al.
Journal of the American Chemical Society, 130(3), 901-906 (2008-01-01)
Density functional theory studies on a series of Fe2(CO)6(PX)2 derivatives show the tetrahedrane to be the most stable for the alkyl (X = Me, tBu), P-H (X = H), and chloro (X = Cl) derivatives. However, butterfly diradical and planar
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