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Merck
CN
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文件

195332

Sigma-Aldrich

1-溴十四烷

97%

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别名:
十四烷基溴, 肉豆蔻基溴
线性分子式:
CH3(CH2)13Br
CAS号:
112-71-0
分子量:
277.28
Beilstein:
1742640
EC 号:
203-999-3
MDL编号:
MFCD00000228
UNSPSC代码:
12352100
PubChem化学物质编号:
24851686
NACRES:
NA.22

质量水平

200

检测方案

97%

形式

liquid

折射率

n20/D 1.460 (lit.)

bp

175-178 °C/20 mmHg (lit.)

mp

5-6 °C (lit.)

密度

0.932 g/mL at 25 °C (lit.)

SMILES字符串

CCCCCCCCCCCCCCBr

InChI

1S/C14H29Br/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15/h2-14H2,1H3

InChI key

KOFZTCSTGIWCQG-UHFFFAOYSA-N

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应用

1-溴十四烷可用于合成：
  • 十四烷基二茂铁
  • 阳离子和两性离子双子表面活性剂
  • 基于双[η1(N)-3,4-二烷氧基亚苄基-4′-十二烷基氧基苯胺]二氯钯 (II) 的带有辛基、癸基、十二烷基、十四烷基和十六烷基烷基的金属配位聚合物
  • 9-十四烷基咔唑

WGK

WGK 3

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Novel Metallomesogenic Polymers Derived from ? 1-Benzylideneaniline Palladium (II) Complex.
Lee M, et al.
Macromolecules, 32(8), 2777-2782 (1999)
Atakilt Abebe et al.
Bioinorganic chemistry and applications, 2018, 8097483-8097483 (2018-08-18)
New organic salts were synthesized by quaternizing 1,10-phenanthroline using 1-bromotetradecane. The first step yielded an organic salt of formula [C26H37N2]Br. Anion exchange reaction using Li[(CF3SO2)2N] resulted in a more stable salt of formula [C26H37N2][(CF3SO2)2N]. The organic salts were investigated by
R Hernández-Bravo et al.
The journal of physical chemistry. B, 122(15), 4325-4335 (2018-03-29)
A combined study for understanding the molecular interactions of asphaltenes with molecular species such as ionic liquids (ILs) comprised experimental measurements and computational numerical simulation calculations, using density-functional theory (DFT) with dispersion corrections, molecular dynamics (MD) calculations, and experimental rheological
Nusrat Jahan et al.
The Journal of organic chemistry, 74(20), 7762-7773 (2009-09-18)
Simple strategies for the synthesis of five series of cationic gemini surfactants and one series of zwitterionic gemini surfactants from pentaerythritol have been developed. Two lipophilic groups were introduced onto pentaerythritol by alkylation of the known compound, O-benzylidenepentaerythritol, with 1-bromooctane
Katrin Wedeking et al.
Langmuir : the ACS journal of surfaces and colloids, 22(7), 3161-3165 (2006-03-22)
Tetradecylferrocene (4, Fc-(CH2)13CH3) was synthesized via lithiation of ferrocene by treatment with tert-butyl lithium, followed by alkylation with 1-bromotetradecane. Complex 4 forms a physisorbed ordered molecular monolayer on the surface of highly oriented pyrolytic graphite (HOPG) that was analyzed by
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