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质量水平
方案
≥99.0% (GC)
包含
20 ppm 4-methoxyphenol as stabilizer
折射率
n20/D 1.410
密度
0.899 g/mL at 20 °C
官能团
ester
储存温度
2-8°C
SMILES字符串
CCCC(=O)OC=C
InChI
1S/C6H10O2/c1-3-5-6(7)8-4-2/h4H,2-3,5H2,1H3
InChI key
MEGHWIAOTJPCHQ-UHFFFAOYSA-N
一般描述
Vinyl butyrate causes the transesterification of natural flavonoid bergenin immobilized onto carboxylic acid functionalized controlled pore glass.
应用
Vinyl butyrate was used as acyl donor in the synthesis of citronellyl esters (acetate, propionate, butyrate, caprate and laurate) using immobilized Candida antarctical ipase B.
警示用语:
Danger
危险声明
危险分类
Acute Tox. 4 Inhalation - Flam. Liq. 2
储存分类代码
3 - Flammable liquids
WGK
WGK 2
闪点(°F)
68.0 °F - closed cup
闪点(°C)
20 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
M Holmquist et al.
Journal of protein chemistry, 14(4), 217-224 (1995-05-01)
To reveal the functional role of Glu87 and Trp89 in the lid of Humicola lanuginosa lipase, site-directed mutagenesis at Glu87 and Trp89 was carried out. The catalytic performance of wild-type and mutated lipases was studied in transesterification reactions in cyclohexane
Betzaida Castillo et al.
Biotechnology and bioengineering, 94(3), 565-574 (2006-02-24)
Enzymes are attractive catalysts for the production of optically active compounds in organic solvents. However, their often low catalytic activity in such applications hampers their practical use. To overcome this, we investigated the effectiveness of the covalent modification of alpha-chymotrypsin
Ionic liquids improve citronellyl ester synthesis catalyzed by immobilized Candida antarctica lipase B in solvent-free media.
Lozano P, et al.
Green Chemistry, 9(7), 780-784 (2007)
Giulia Martelli et al.
Bioorganic chemistry, 88, 102975-102975 (2019-05-19)
Obtainment and testing of pure enantiomers are of great importance for bioactive compounds, because of the assessed implications of enantioselectivity in receptor-mediated responses. Herein we evaluated the use of biocatalysis to obtain enantiomerically pure β-lactam intermediates further exploited in the
Mozaffar Shakeri et al.
Journal of biotechnology, 145(3), 281-283 (2009-12-02)
We examined the activity of free Rhizopus oryzae lipase (ROL) and ROL immobilized on mesoporous materials in transesterification reactions in various dialkylimidazolium-cation based ionic liquids. For free ROL, the highest activity (0.39 U/mg protein) was obtained in [OMIm][PF(6)] followed by
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