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Merck
CN

191744

Sigma-Aldrich

3-甲基-1-苯基-2-磷 1-氧化物

85%, technical grade

别名:

1-氧代-3-甲基-1-苯基-2-磷烯, 2,3-二氢-4-甲基-1-苯磷-1-氧化物, MPPO, NSC 107634

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About This Item

经验公式(希尔记法):
C11H13OP
CAS号:
分子量:
192.19
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22

等级

technical grade

方案

85%

反应适用性

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling

杂质

5% dichloromethane

折射率

n20/D 1.5707 (lit.)

沸点

150 °C/0.15 mmHg (lit.)

SMILES字符串

CC1=CP(=O)(CC1)c2ccccc2

InChI

1S/C11H13OP/c1-10-7-8-13(12,9-10)11-5-3-2-4-6-11/h2-6,9H,7-8H2,1H3

InChI key

YMKWWHFRGALXLE-UHFFFAOYSA-N

应用

用于催化:
  • 分子内 aza-Wittig 环化反应
  • 聚合反应

反应物用于制备:
  • 抗癌磷糖及其溴化衍生物

象形图

Health hazardExclamation mark

警示用语:

Warning

危险声明

危险分类

Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

235.4 °F - closed cup

闪点(°C)

113 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Phuong-Mai Nguyen et al.
Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment, 34(10), 1703-1720 (2017-04-05)
Migration due to indirect contact with packaging caused several major sanitary crises, including the spread contamination of dry food by mineral oils and printing ink constituents from cardboard. The issues are still not fully resolved because the mechanisms have been
Andrea Walzl et al.
Molecules (Basel, Switzerland), 25(15) (2020-08-06)
The current demand to cut back on the use of plastic materials has brought a major boost to the search for bio-based alternatives. Not only are plastic bags and primary food packaging under scrutiny here, but also those materials used

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