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质量水平
方案
98%
表单
liquid
折射率
n20/D 1.395 (lit.)
沸点
89-90 °C (lit.)
密度
0.862 g/mL at 25 °C (lit.)
官能团
acetal
ether
SMILES字符串
COC(OC)C=C
InChI
1S/C5H10O2/c1-4-5(6-2)7-3/h4-5H,1H2,2-3H3
InChI key
OBWGMYALGNDUNM-UHFFFAOYSA-N
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一般描述
Acrolein dimethyl acetal undergoes cationic α-diimine palladium chelate catalyzed copolymerization with ethene to yield branched copolymers.
应用
Acrolein dimethyl acetal was used in the facile one step synthesis of 4-hydroxy-2E-nonenal and its dimethyl acetal via a cross-metathesis reaction with octen-3-ol.
Weidong Li et al.
Journal of the American Chemical Society, 126(39), 12246-12247 (2004-09-30)
Acrolein dimethyl acetal (ADMA) can be copolymerized with ethene using a cationic alpha-diimine palladium chelate catalyst to yield branched copolymers. Catalyst deactivation occurs via methanol elimination to give an inert eta3-1-methoxyallyl palladium species. This process can be retarded by the
Laurent Soulère et al.
Chemistry and physics of lipids, 150(2), 239-243 (2007-10-05)
The facile one step synthesis of 4-hydroxy-2E-nonenal and its dimethyl acetal via a cross-metathesis reaction between commercially available octen-3-ol and acrolein or its dimethyl acetal is reported. The method was extended to the synthesis of C6 and C12 4-hydroxy-2E-enals, their
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