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Merck
CN

190144

Sigma-Aldrich

氯铬酸吡啶盐

98%

别名:

PCC

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About This Item

线性分子式:
C5H6NClCrO3
CAS号:
分子量:
215.56
Beilstein:
7054643
EC 号:
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

98%

表单

solid

反应适用性

reagent type: oxidant

mp

205-208 °C (lit.)

SMILES字符串

O[Cr](Cl)(=O)=O.c1ccncc1

InChI

1S/C5H5N.ClH.Cr.H2O.2O/c1-2-4-6-5-3-1;;;;;/h1-5H;1H;;1H2;;/q;;+2;;;/p-2

InChI key

JWIPGAFCGUDKEY-UHFFFAOYSA-L

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一般描述

PCC是一种重要的有机试剂,用于氧化反应。

应用

用于由 D-葡萄糖经 Grubbs 催化闭环复分解反应合成 α,ß-不饱和内酯过程中氧化烯丙基亚甲基。
稳定的多功能氧化剂,用于醇类的温和选择性氧化。

警示用语:

Danger

危险分类

Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Ox. Sol. 2 - Skin Sens. 1

储存分类代码

5.1B - Oxidizing hazardous materials

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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分析证书(COA)

Lot/Batch Number

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Recent advances in application of pyridinium chlorochromate (PCC) in organic synthesis
M Heravi M, et al.
Current Organic Synthesis, 13(2), 220-254 (2016)
Perrine Ferré et al.
Language, cognition and neuroscience, 34(8), 949-972 (2019-08-29)
Most of the current knowledge about age-related differences in brain neurofunctional organization stems from neuroimaging studies using either a "resting state" paradigm, or cognitive tasks for which performance decreases with age. However, it remains to be known if comparable age-related
Cheryl Peters et al.
Pediatric critical care medicine : a journal of the Society of Critical Care Medicine and the World Federation of Pediatric Intensive and Critical Care Societies, 19(8), e394-e402 (2018-06-26)
We evaluated adapting the quick Sequential (Sepsis-Related) Organ Failure Assessment score (fast respiratory rate, altered mental status, low blood pressure) for pediatric use by selecting thresholds from three commonly used definitions: Pediatric Logistic Organ Dysfunction 2, Pediatric Advanced Life Support
Tetrahedron, 62, 11165-11165 (2006)
Anna M Larsson et al.
Journal of experimental botany, 68(14), 3857-3867 (2017-04-04)
Cyanobacterial CO2 fixation is promoted by encapsulating and co-localizing the CO2-fixing enzymes within a protein shell, the carboxysome. A key feature of the carboxysome is its ability to control selectively the flux of metabolites in and out of the shell.

商品

Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis

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