189316
3-氯-2,2-二甲基-1-丙醇
99%
别名:
2-氯甲基-2-甲基-1-丙醇
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关于此项目
线性分子式:
ClCH2C(CH3)2CH2OH
化学文摘社编号:
分子量:
122.59
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
236-488-9
MDL number:
产品名称
3-氯-2,2-二甲基-1-丙醇, 99%
InChI key
CAZPRAORHCOIHC-UHFFFAOYSA-N
InChI
1S/C5H11ClO/c1-5(2,3-6)4-7/h7H,3-4H2,1-2H3
SMILES string
CC(C)(CO)CCl
assay
99%
refractive index
n20/D 1.45 (lit.)
bp
87 °C/35 mmHg (lit.)
mp
34-36 °C (lit.)
functional group
chloro
hydroxyl
Quality Level
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Application
3-Chloro-2,2-dimethyl-1-propanol has been used in combinatorial preparation of new aroma-impact compounds such as polyfunctional thiols.
General description
3-Chloro-2,2-dimethyl-1-propanol undergoes oxidation with pyridinium chlorochromate to yield 3-chloro-2,2-dimethylpropanal which spontaneously trimerizes to s-trioxane.
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
159.8 °F - closed cup
flash_point_c
71 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
2, 4, 6-Tri (2'-chloro-1', 1'-dimethylethyl)-s-trioxane: Synthesis, Spectroscopy and Crystal Structure.
Tarbutton GL and Valente EJ.
Journal of Chemical Crystallography, 40(2), 126-129 (2010)
Xin Min et al.
Royal Society open science, 5(5), 180156-180156 (2018-06-13)
A novel alkyl lithium-based initiator with relatively large steric hindrance, tert-butyldimethylsiloxydimethylpropyl lithium (TBDMSODPrLi), was designed and synthesized. By using TBDMSODPrLi, hydroxyl-terminated polybutadiene (HTPB) was prepared via anionic polymerization. The macromolecular structure of HTPB was characterized and verified by FTIR and
Catherine Vermeulen et al.
Combinatorial chemistry & high throughput screening, 9(8), 583-590 (2006-10-05)
Combinatorial chemistry was shown to be an efficient tool for the preparation of new aroma-impact compounds. In this case, polyfunctional thiols were synthesized quickly using halide reagents or Bunte salt intermediates. They were separated by gas chromatography and then characterized
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