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质量水平
方案
98%
表单
solid
mp
81-83 °C (lit.)
官能团
chloro
SMILES字符串
Nc1ccc(Cl)nc1
InChI
1S/C5H5ClN2/c6-5-2-1-4(7)3-8-5/h1-3H,7H2
InChI key
QAJYCQZQLVENRZ-UHFFFAOYSA-N
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一般描述
5-氨基-2-氯吡啶可与空间受阻的2,6-二甲基苯基硼酸进行Suzuki-Miyaura偶联。它可通过Sandmeyer反应利用溴化物对氯化物进行易受温度影响的置换反应而生成2,5-二溴吡啶。
应用
5-氨基-2-氯吡啶已被用于合成[2H5]2-氨基-l-甲基-6-苯基咪唑[4,5-b]吡啶。它已被用于鉴定和评估分子印迹聚合物，用于从药物中选择性去除潜在的遗传毒性氨基吡啶杂质。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Fast identification of selective resins for removal of genotoxic aminopyridine impurities via screening of molecularly imprinted polymer libraries.
Kecili R, et al. et al.
Journal of Chromatography A (2014)
A M Lynch et al.
Cancer research, 52(22), 6216-6223 (1992-11-15)
During the cooking of beef, the genotoxic heterocyclic aromatic amines 2-amino-3,8-dimethylimidazo[4,5-f]quinoxaline (MeIQx), 2-amino-3,4,8-trimethylimidazo[4,5-f]quinoxaline (DiMeIQx), and 2-amino-1-methyl-6-phenylimidazo[4,5-b]pyridine (PhIP) are formed. Little is known about the fate of these compounds in humans or the factors affecting it. We have developed assays based
Unexpected Displacements of Chloride by Bromide Found During Sandmeyer Reactions of 3-or 5-Amino-2-chloropyridines.
Krapcho AP and Haydar SN.
Heterocyclic Communications, 4(4), 291-292 (1998)
A highly active catalyst for Suzuki-Miyaura cross-coupling reactions of heteroaryl compounds.
Kelvin L Billingsley et al.
Angewandte Chemie (International ed. in English), 45(21), 3484-3488 (2006-04-28)
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