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Merck
CN

187240

Sigma-Aldrich

9-蒽甲醇

97%

别名:

9-(羟甲基)蒽

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About This Item

经验公式(希尔记法):
C15H12O
CAS号:
分子量:
208.26
Beilstein:
1873402
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

97%

溶解性

chloroform: soluble 20 mg/mL, clear to slightly hazy, light yellow to yellow

官能团

hydroxyl

SMILES字符串

OCc1c2ccccc2cc3ccccc13

InChI

1S/C15H12O/c16-10-15-13-7-3-1-5-11(13)9-12-6-2-4-8-14(12)15/h1-9,16H,10H2

InChI key

JCJNNHDZTLRSGN-UHFFFAOYSA-N

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一般描述

9-蒽甲醇参与由氧化铝烷催化的L-丙交酯的开环聚合反应。它与-丁醇钾发生质子交换反应,生成9-蒽甲醇

9-蒽甲醇是蒽的衍生物,常用于Diels-Alder反应。

应用

9-蒽甲醇可用于:
  • 作为制备9-蒽甲基-1-哌嗪羧酸酯的起始原料,充当HPLC测定异氰酸酯的试剂。
  • Diels-Alder 反应,与二甲基乙炔-二羧酸酯反应生成内酯衍生物。
  • 作为δ-戊内酯开环聚合反应引发剂,合成聚((δ-戊内酯)。
  • 作为合成聚合物载体蒽的起始材料,在环加成反应中充当亲二烯体清除剂。

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)


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分析证书(COA)

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访问文档库

Cyclodextrin-promoted Diels Alder reactions of a polycyclic aromatic hydrocarbon under mild reaction conditions
Chaudhuri, et al.
Tetrahedron Letters, 56, 1619-1623 (2015)
Yuzhan Li et al.
Scientific reports, 10(1), 20214-20214 (2020-11-21)
The development of multi-stimuli-responsive shape memory polymers has received increasing attention because of its scientific and technological significance. In this work, epoxy elastomers with reversible crosslinks are synthesized by polymerizing an anthracene-functionalized epoxy monomer, a diepoxy comonomer, and a dicarboxylic
Shanshan Kou et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 96, 768-775 (2012-08-14)
Vibrational spectral measurements were made for 9-anthracenemethanol. Optimized geometrical structure and harmonic vibration frequencies were computed based on ab initio and density functional theory B3LYP methods using 6-311G(**) and LANL2DZ basis sets. The equilibrium geometries got from all of the
Development of a new approach for total isocyanate determination using the reagent 9-anthracenylmethyl-1-piperazinecarboxylate.
Roh Y-M, et al.
Analyst, 125(9), 1691-1696 (2000)
Living cationic polymerization of δ-valerolactone and synthesis of high molecular weight homopolymer and asymmetric telechelic and block copolymer
Lou X, et al.
Macromolecules, 35, 1190-1195 (2002)

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