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质量水平
方案
97%
溶解性
chloroform: soluble 20 mg/mL, clear to slightly hazy, light yellow to yellow
官能团
hydroxyl
SMILES字符串
OCc1c2ccccc2cc3ccccc13
InChI
1S/C15H12O/c16-10-15-13-7-3-1-5-11(13)9-12-6-2-4-8-14(12)15/h1-9,16H,10H2
InChI key
JCJNNHDZTLRSGN-UHFFFAOYSA-N
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一般描述
9-蒽甲醇参与由氧化铝烷催化的L-丙交酯的开环聚合反应。它与叔-丁醇钾发生质子交换反应，生成9-蒽甲醇。
9-蒽甲醇是蒽的衍生物，常用于Diels-Alder反应。
9-蒽甲醇是蒽的衍生物，常用于Diels-Alder反应。
应用
9-蒽甲醇可用于：
- 作为制备9-蒽甲基-1-哌嗪羧酸酯的起始原料，充当HPLC测定异氰酸酯的试剂。
- Diels-Alder 反应,与二甲基乙炔-二羧酸酯反应生成内酯衍生物。
- 作为δ-戊内酯开环聚合反应引发剂，合成聚（(δ-戊内酯)。
- 作为合成聚合物载体蒽的起始材料，在环加成反应中充当亲二烯体清除剂。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Cyclodextrin-promoted Diels Alder reactions of a polycyclic aromatic hydrocarbon under mild reaction conditions
Chaudhuri, et al.
Tetrahedron Letters, 56, 1619-1623 (2015)
Development of a new approach for total isocyanate determination using the reagent 9-anthracenylmethyl-1-piperazinecarboxylate.
Roh Y-M, et al.
Analyst, 125(9), 1691-1696 (2000)
Synthesis of a polymer-supported anthracene and its application as a dienophile scavenger
Lei X and Porco JA
Organic Letters, 6, 795-798 (2004)
J W Flesher et al.
Biochemical and biophysical research communications, 251(1), 239-243 (1998-10-29)
The role of electrophilic hydroxymethyl sulfate esters in the metabolic activation, DNA-damage, mutagenicity, and complete carcinogenicity of polycyclic aromatic hydrocarbons has been elucidated considerably in recent years. The observations are in agreement with a unified hypothesis which predicts that electrophilic
Tamuka Chidanguro et al.
Dalton transactions (Cambridge, England : 2003), 47(26), 8663-8669 (2018-06-23)
We report on the use of visible light as the driving force for the intramolecular dimerization of pendant anthracene groups on a methacrylic polymer to induce the formation of single-chain nanoparticles (SCNPs). Using a 532 nm green laser light source
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