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安全信息

187135

Sigma-Aldrich

异烟酸 N-氧化物

99%

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About This Item

经验公式（希尔记法）:
C6H5NO3
CAS号:
13602-12-5
分子量:
139.11
EC 号:
237-086-6
MDL编号:
MFCD00006209
UNSPSC代码:
12352100
PubChem化学物质编号:
24851255

方案

99%

mp

270-271 °C (lit.)

SMILES字符串

OC(=O)c1cc[n+]([O-])cc1

InChI

1S/C6H5NO3/c8-6(9)5-1-3-7(10)4-2-5/h1-4H,(H,8,9)

InChI key

QCWTWMJMLSKQCJ-UHFFFAOYSA-N

一般描述

Isonicotinic acid N-oxide interacts with 3d metal(II) perchlorates in ethanol-triethyl orthoformate leading to partial substitution of perchlorate with isonicotinate-N-oxide anionic groups[1]. It reacts with AgClO4 or AgBF4 to yield distinct crystalline products[2]. It forms polymeric lanthanide(III) complexes[3].

应用

Isonicotinic acid N-oxide was used in the synthesis of three-dimensional coordination polymers based on inorganic lanthanide(II) sulfate skeletons[4].

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H315,H319,H335

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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    分析证书(COA)

    Lot/Batch Number
    MKBJ6512V
    08606DD
    14523PZ
    12314BO
    12116BU

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    Nasrin Shokouhfar et al.
    Dalton transactions (Cambridge, England : 2003), 47(41), 14549-14555 (2018-09-27)
    Considering the widespread production of Cr(vi) from various industrial processes and its damaging toxicity as a carcinogenic agent, it is imperative to investigate stable and efficient adsorbents with a rapid performance towards Cr(vi) adsorption. Zirconium-containing metal-organic frameworks (Zr-MOFs) have been
    Zheng He et al.
    Inorganic chemistry, 44(4), 862-874 (2005-04-30)
    Fourteen three-dimensional coordination polymers of general formula [Ln(lNO)(H2O)(SO4)]n, where Ln = La, 1.La; Ce, 2.Ce; Pr, 3.Pr; Nd, 4.Nd; Sm, 5.Sm; Eu, 6.Eu; Gd, 7.Gd; Tb, 8.Tb; Dy, 9.Dy; Ho, 10.Ho; Er. 11.Er; Tm, 12.Tm; Yb, 13.Yb; and Lu, 14.Lu;
    Unusual anion effect on the direction of three-dimensional (3-D) channel-like silver (I) coordination frameworks with isonicotinic acid N-oxide.
    Du M, et al.
    CrystEngComm, 11(8), 1536-1540 (2009)
    Structural characterization and luminescence studies of new lanthanide (III) complexes with nicotinic and isonicotinic acid N-oxides.
    Mao J-G, et al.
    Polyhedron, 17(23), 3999-4009 (1998)
    Nicotinic and isonicotinic acid n-oxide interactions with 3d metal perchlorates [1].
    Gelfand LS, et al.
    J. Inorg. Nucl. Chem., 42(3), 377-385 (1980)

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