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Merck
CN

187070

Sigma-Aldrich

2-溴苄基溴

98%

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别名:
α,2-二溴甲苯
线性分子式:
BrC6H4CH2Br
CAS号:
分子量:
249.93
Beilstein:
971015
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

98%

形式

solid

折射率

n20/D 1.619 (lit.)

bp

129 °C/19 mmHg (lit.)

mp

29-32 °C (lit.)

溶解性

dioxane: soluble 1 g/10 mL, clear, colorless

SMILES字符串

BrCc1ccccc1Br

InChI

1S/C7H6Br2/c8-5-6-3-1-2-4-7(6)9/h1-4H,5H2

InChI key

LZSYGJNFCREHMD-UHFFFAOYSA-N

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一般描述

2-溴苄溴化物是一种试剂,用于保护酮和醛在其反应性较低的醇氧化状态,并在各种反应中用作偶联组分。

应用

2-溴苄溴用于合成:
  • 取代喹唑啉和 1,2,3,4-四氢喹唑啉
  • 2-和 3-取代茚
  • -2-溴三苄胺

象形图

Corrosion

警示用语:

Danger

危险声明

危险分类

Eye Dam. 1 - Skin Corr. 1B

WGK

WGK 3

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Synthesis and structural studies of tris-2-chlorobenzylamine and tris-2-bromobenzylamine.
Chen Q, , et al.
Journal of Chemical Crystallography, 35(3), 177-181 (2005)
2-Bromobenzyl Bromide
Pfeifer LA
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Xuesen Fan et al.
Chemistry, an Asian journal, 9(3), 739-743 (2014-01-01)
An efficient synthesis of diversely substituted quinazolines and 1,2,3,4-tetrahydroquinazolines through copper-catalyzed tandem reactions of the readily available 2-bromobenzyl bromides, aldehydes, and aqueous ammonia or amines has been developed. By using ammonia and simple aliphatic amines as the nitrogen source, the
Efficient synthesis of 2-and 3-substituted indenes from 2-bromobenzyl bromide through an enolate alkylation/Cr (II)/Ni (II)-mediated carbonyl addition sequence.
Halterman RLand Zhu C.
Tetrahedron Letters, 40(42), 7445-7448 (1999)
Prachi Singh et al.
SLAS discovery : advancing life sciences R & D, 22(4), 440-446 (2017-03-23)
Analysis of interactions between molecules is of fundamental importance in life science research. In this study, we applied weak affinity chromatography, based on high-performance liquid chromatography and mass spectrometry, as a powerful tool for direct analysis of the components of

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