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质量水平
方案
96%
旋光性
[α]25/D +10°, c = 10 in H2O
光学纯度
ee: 95% (GLC)
折射率
n20/D 1.4548 (lit.)
沸点
81 °C/8 mmHg (lit.)
mp
30-32 °C (lit.)
密度
0.926 g/mL at 25 °C (lit.)
官能团
amine
hydroxyl
储存温度
2-8°C
SMILES字符串
CC(C)[C@H](N)CO
InChI
1S/C5H13NO/c1-4(2)5(6)3-7/h4-5,7H,3,6H2,1-2H3/t5-/m1/s1
InChI key
NWYYWIJOWOLJNR-RXMQYKEDSA-N
应用
(S)-(+)-2-氨基-3-甲基-1-丁醇可用于制备：
- 亚胺和噁唑啉（分别通过与醛和腈反应生成）。
- 含环三磷腈基元的手性噁唑啉衍生多齿配体。
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
172.4 °F - closed cup
闪点(°C)
78 °C - closed cup
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Journal of the Chemical Society. Perkin Transactions 1, 192-192 (1989)
Tetrahedron Letters, 34, 2015-2015 (1993)
Asymmetric synthesis of alpha-substituted o-methoxybenzyl alcohols via stereoselective additions to kinetically resolved o-anisaldehyde (tricarbonyl) chromium
Davies SG and Goodfellow CL
Journal of the Chemical Society. Perkin Transactions 1, 1, 192-194 (1989)
Enantioselective palladium catalysed allylic substitution with thienyl oxazoline ligands
Frost CG and Williams JMJ
Tetrahedron Letters, 34(12), 2015-2018 (1993)
Dheeraj Kumar et al.
Dalton transactions (Cambridge, England : 2003), 43(37), 13899-13912 (2014-08-12)
Chiral oxazoline based bi and hexadentate ligands built on cyclophosphazene cores have been synthesized and characterized. (NPPh2)2[NP(m-OC6H4C(O)OCH3)2] (1) was prepared by the reaction of gem-(NPPh2)2(NPCl2) with methyl-3-hydroxy benzoate in the presence of Cs2CO3. Compound 1 was converted to the dicarboxylic
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