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Merck
CN

186090

Sigma-Aldrich

N-甲基高哌嗪

97%

别名:

六氢-1-甲基-1H-1,4-二氮杂卓

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About This Item

经验公式(希尔记法):
C6H14N2
CAS号:
分子量:
114.19
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

97%

表单

liquid

折射率

n20/D 1.477 (lit.)

沸点

74-75 °C/35 mmHg (lit.)

密度

0.918 g/mL at 25 °C (lit.)

储存温度

−20°C

SMILES字符串

CN1CCCNCC1

InChI

1S/C6H14N2/c1-8-5-2-3-7-4-6-8/h7H,2-6H2,1H3

InChI key

FXHRAKUEZPSMLJ-UHFFFAOYSA-N

一般描述

1-甲基高哌嗪与一系列重氮盐发生偶联反应,生成 4-甲基-1-[2-芳基-1-二氮基]-1,4-二氮基

应用

1-甲基高哌嗪用于合成以下物质:
  • 具有药理活性的新型苯并咪唑衍生物
  • 铂(II)取代的二硫配合物

警示用语:

Danger

危险声明

危险分类

Acute Tox. 4 Oral - Flam. Liq. 3 - Skin Corr. 1B

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

113.0 °F - closed cup

闪点(°C)

45 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Synthesis and characterization of a series of 4-methyl-1-[2-aryl-1-diazenyl]-1, 4-diazepanes and 1, 4-di-[2-aryl-1-diazenyl]-1, 4-diazepanes.
Moser SL and Vaughan K.
Canadian Journal of Chemistry, 82(!2), 1725-1735 (2004)
H Nakano et al.
Bioorganic & medicinal chemistry, 8(2), 373-380 (2000-03-18)
Novel benzimidazole derivatives were synthesized and their pharmacological activities were examined. These compounds showed a good suppressive action on histamine release from rat peritoneal mast cells produced by antigen-antibody reaction, an antagonistic action on guinea pig ileum contraction caused by
Homopiperazine platinum (II) complexes containing substituted disulfide groups: crystal structure of [Pt II(homopiperazine)(diphenylsulfide) Cl] NO3.
Ali MS, et al.
Polyhedron, 21(1), 125-131 (2002)
Son T Nguyen et al.
Bioorganic & medicinal chemistry, 23(9), 2024-2034 (2015-03-31)
Recently we described a novel pyranopyridine inhibitor (MBX2319) of RND-type efflux pumps of the Enterobacteriaceae. MBX2319 (3,3-dimethyl-5-cyano-8-morpholino-6-(phenethylthio)-3,4-dihydro-1H-pyrano[3,4-c]pyridine) is structurally distinct from other known Gram-negative efflux pump inhibitors (EPIs), such as 1-(1-naphthylmethyl)-piperazine (NMP), phenylalanylarginine-β-naphthylamide (PAβN), D13-9001, and the pyridopyrimidine derivatives. Here

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