185590
丙腈
99%
别名:
乙基氰
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线性分子式:
CH3CH2CN
化学文摘社编号:
分子量:
55.08
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-464-4
Beilstein/REAXYS Number:
773680
MDL number:
产品名称
丙腈, 99%
InChI key
FVSKHRXBFJPNKK-UHFFFAOYSA-N
InChI
1S/C3H5N/c1-2-3-4/h2H2,1H3
SMILES string
CCC#N
assay
99%
form
liquid
refractive index
n20/D 1.366 (lit.)
bp
97 °C (lit.)
mp
−93 °C (lit.)
solubility
water: soluble 11.9g/100g at 40 °C
water: soluble 29g/100g at 100 °C
DMF: miscible
alcohol: miscible
diethyl ether: miscible
density
0.772 g/mL at 25 °C (lit.)
functional group
nitrile
Quality Level
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Application
丙腈被用于介孔石墨C3N4催化的各种腈的环三聚反应，生成三嗪衍生物。它被用于研究邻甲酚与丙腈的复合物形成的拉曼光谱。
General description
丙腈是一种实验性十二指肠溃疡诱导剂，能够刺激大鼠胃酸分泌。
signalword
Danger
Hazard Classifications
Acute Tox. 2 Dermal - Acute Tox. 2 Oral - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
42.8 °F - closed cup
flash_point_c
6 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
Pathogenesis of duodenal ulcer. Gastric hyperacidity caused by propionitrile and cysteamine in rats.
S Szabo et al.
Research communications in chemical pathology and pharmacology, 16(2), 311-323 (1977-02-01)
Cysteamine and propionitrile, experimental duodenal ulcerogens, stimulated gastric acid secretion in the rat. Gastric acid secretion was measured by two separate methods, the conventional pylorus ligation technique and a non-invasive technique based on the pH dependent liberation of azure A
A Raman spectroscopic study of complex formation between o-cresol and propionitrile.
Girling RB and Shurvell HF.
Vibrational Spectroscopy, 18(1), 77-82 (1998)
Mesoporous graphitic carbon nitride as a versatile, metal-free catalyst for the cyclisation of functional nitriles and alkynes.
Goettmann F, et al.
New. J. Chem., 31(8), 1455-1460 (2007)
David Crich et al.
Carbohydrate research, 341(10), 1467-1475 (2006-04-29)
It is shown that the use of 5% acetonitrile or propionitrile in dichloromethane functions to increase the beta-selectivity of a number of L-rhamnopyranosylation reactions conducted by the thioglycoside method with activation by the 1-benzenesulfinyl piperidine/trifluoromethanesulfonic anhydride couple. The use of
Oliver Kaumanns et al.
The Journal of organic chemistry, 74(1), 75-81 (2008-11-27)
The rates of the reactions of the colored para-substituted phenylacetonitrile anions 1a-c and the phenylpropionitrile anions 2a-c with Michael acceptors (3a-u) were determined by UV-vis spectroscopy in DMSO at 20 degrees C. The reactions follow second-order kinetics, and the corresponding
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