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About This Item
线性分子式:
CH3C(CH2Cl)2CO2H
CAS号:
分子量:
171.02
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
质量水平
检测方案
≥97%
形式
solid
mp
64-66 °C (lit.)
SMILES字符串
CC(CCl)(CCl)C(O)=O
InChI
1S/C5H8Cl2O2/c1-5(2-6,3-7)4(8)9/h2-3H2,1H3,(H,8,9)
InChI key
DDSPBKFTRPWDLI-UHFFFAOYSA-N
一般描述
3,3′-Dichloropivalic acid reacts with ethane-1,2-diamine to yield isomeric tetra-amine derivatives, tetra amino carboxylic acid and carboxamidotriamino alcohol.
应用
3,3′-Dichloropivalic acid was used in the synthesis of 3,3′-dichloropivaloyl chloride.
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
A novel rearrangement reaction conversion of 3-(chloromethyl) azetidin-2-ones to azetidine-3-carboxylic acid esters.
Bartholomew D and Stocks MJ.
Tetrahedron Letters, 32(36), 4795-4798 (1991)
Paul V Bernhardt et al.
Inorganic chemistry, 43(5), 1681-1688 (2004-03-03)
Reaction between ethane-1,2-diamine and 3,3'-dichloropivalic acid results in different, isomeric tetra-amine derivatives, one a tetraamino carboxylic acid and the other a carboxamidotriamino alcohol, depending upon reaction conditions. Intended conversion of the Cu(II) complex of the former to a cyclam-like macrocycle
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