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质量水平
方案
97%
表单
liquid
折射率
n20/D 1.435 (lit.)
沸点
87-89 °C (lit.)
密度
0.98 g/mL at 25 °C (lit.)
官能团
chloro
SMILES字符串
ClCC1CC1
InChI
1S/C4H7Cl/c5-3-4-1-2-4/h4H,1-3H2
InChI key
ZVTQWXCKQTUVPY-UHFFFAOYSA-N
一般描述
(Chloromethyl)cyclopropane on reaction with isolable dialkylsilylene affords 5-silaspiro[4.4]nonane derivative.
应用
(Chloromethyl)cyclopropane was used in the synthesis of (lithiomethyl)cyclopropane and homoallyllithium via 4,4′-di-tert-butylbiphenyl or naphthalene-catalysed lithiation reaction.
警示用语：
Danger
危险分类
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
28.4 °F - closed cup
闪点(°C)
-2 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Unexpected reactions of an isolable dialkylsilylene with Haloalkanes.
Ishida S, et al.
Chemistry Letters (Jpn), 11, 1102-1103 (2001)
Easy selective generation of (lithiomethyl) cyclopropane or homoallyllithium by a chlorine-lithium exchange.
Pastor IM, et al.
Tetrahedron Letters, 49(48), 6870-6872 (2008)
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