所有图片(2)
About This Item
线性分子式:
BrC6H4CH2OH
CAS号:
分子量:
187.03
Beilstein:
2243418
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
99%
表单
solid
mp
78-80 °C (lit.)
官能团
bromo
hydroxyl
SMILES字符串
OCc1ccccc1Br
InChI
1S/C7H7BrO/c8-7-4-2-1-3-6(7)5-9/h1-4,9H,5H2
InChI key
IOWGHQGLUMEZKG-UHFFFAOYSA-N
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应用
2-Bromobenzyl alcohol was used in microwave assisted palladium-catalyzed synthesis of phthalides. It was also used in the synthesis of 1-hydroxy-3(1H)-l,2-benzoboroxole.
警示用语：
Warning
危险声明
危险分类
Acute Tox. 4 Oral - Eye Irrit. 2
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves
Synthesis and structure of benzoboroxoles: novel organoboron heterocycles.
Zhdankin VV, et al.
Tetrahedron Letters, 40(37), 6705-6708 (1999)
Fast microwave promoted palladium-catalyzed synthesis of phthalides from bromobenzyl alcohols utilizing DMF and Mo (CO)6 as carbon monoxide sources.
Wu X, et al.
Tetrahedron Letters, 45(24), 4635-4638 (2004)
Manas K Ghorai et al.
The Journal of organic chemistry, 79(14), 6468-6479 (2014-06-24)
A simple and unpredicted synthetic pathway toward racemic and scalemic tetrahydrodibenzoimidazoazepines has been invented serendipitously proceeding through an S(N)2-type ring-opening of N-activated aziridines with 2-bromobenzylamine followed by a hitherto unprecedented cascade cyclization reaction sequence comprising a Cu-catalyzed cross dehydrogenation C-N
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