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Merck
CN

18086

1-乙基-3-甲基咪唑甲基硫酸盐

≥98.0% (HPLC)

别名:

[EMIM][MS]

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关于此项目

经验公式(希尔记法):
C7H14N2O4S
化学文摘社编号:
分子量:
222.26
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
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产品名称

1-乙基-3-甲基咪唑甲基硫酸盐, ≥98.0% (HPLC)

InChI

1S/C6H11N2.CH4O4S/c1-3-8-5-4-7(2)6-8;1-5-6(2,3)4/h4-6H,3H2,1-2H3;1H3,(H,2,3,4)/q+1;/p-1

SMILES string

COS([O-])(=O)=O.CCn1cc[n+](C)c1

InChI key

BXSDLSWVIAITRQ-UHFFFAOYSA-M

assay

≥98.0% (HPLC)

composition

carbon, 37.07-38.58%
nitrogen, 12.35-12.85% (as tested by elemental analysis)

impurities

≤0.2% water

Quality Level

Application

[EMIM][MS] may be used as a solvent to synthesize gold nanoparticles via reduction of gold(III) chloride trihydrate [HAuCl4.3H2O] using glycerol as a reducing agent.

General description

1-Ethyl-3-methylimidazolium methyl sulfate [EMIM][MS] when added as an eluent modifier to the mobile phase results in better separation of the three positional isomers of benzoic acid by reversed-phase (RP) high-performance liquid chromatography (HPLC).

pictograms

CorrosionExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Retention factors and resolutions of amino benzoic acid isomers with some lonic liquids.
Zheng J, et al.
Biotechnology and Bioprocess Engineering: BBE, 11(6), 477-483 (2006)
Effects of ionic liquid as additive and the pH of the mobile phase on the retention factors of amino benzoic acids in RP-HPLC.
Zheng J, et al.
Journal of Chromatographic Science, 45(5), 256-262 (2007)
Microwave-assisted separation of ionic liquids from aqueous solution of ionic liquids
Ha, Sung Ho, Ngoc Lan Mai, and Yoon-Mo Koo
Journal of Chromatography A, 1217.49, 7638-7641 (2010)
Automated carboxylesterase assay for the evaluation of ionic liquids? human toxicity
Cunha, Edite, et al.
Journal of Hazardous Materials, 244, 563-569 (2013)
Strong anion effects on gold nanoparticle formation in ionic liquids.
Khare V, et al.
Journal of Materials Chemistry, 20(7), 1332-1339 (2010)

商品

Functionalized imidazolium cations with thioether, urea, or thiourea derivatized side chains act as metal-ligating moieties, whereas the PF6– anions provide the desired water immiscibility.

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