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检测方案
98%
形式
liquid
旋光性
[α]22/D −30.5°, neat
折射率
n20/D 1.4877 (lit.)
bp
94-99 °C/27 mmHg (lit.)
密度
0.915 g/mL at 25 °C (lit.)
SMILES字符串
CC1(C)[C@@]2([H])CC[C@](CN)([H])[C@@]1(C2)[H]
InChI
1S/C10H19N/c1-10(2)8-4-3-7(6-11)9(10)5-8/h7-9H,3-6,11H2,1-2H3/t7-,8-,9-/m0/s1
InChI key
SYJBFPCQIJQYNV-CIUDSAMLSA-N
应用
可能使用(-)-顺式-肉豆蔻胺：
- 作为反应物制备N,N-双（（-）-顺式-肉豆蔻酰基）丁烯-2，3-二亚胺（BMDI），一种可以形成过渡金属配合物以催化不对称合成的双齿二亚胺配体。
- 作为制备咪唑衍生物的基础，咪唑衍生物是有效的和选择性的大麻素受体（CB2）拮抗剂。
- 制备一种手性催化剂，该催化剂可催化不对称的三组分曼氏反应。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
172.4 °F
闪点(°C)
78 °C
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Synthesis of new chiral diimine palladium (II) and nickel (II) complexes bearing oxazoline-and myrtanyl-based nitrogen ligands. Crystal structure of the C 2-symmetric complex [{(1R, 2S)-inda-box} PdCl 2].
Abu-Surrah AS, et al.
Polyhedron, 21(1), 27-31 (2002)
Efficient catalysts for asymmetric Mannich reactions.
Rachwalski M, et al.
Organic & Biomolecular Chemistry, 11(25), 4207-4213 (2013)
Synthesis and SAR of novel imidazoles as potent and selective cannabinoid CB 2 receptor antagonists with high binding efficiencies.
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