质量水平
检测方案
97%
形式
powder
反应适用性
reagent type: reductant
mp
98-100 °C (dec.) (lit.)
SMILES字符串
B.CC(C)(C)N
InChI
1S/C4H11N.BH3/c1-4(2,3)5;/h5H2,1-3H3;1H3
InChI key
GKFJEDWZQZKYHV-UHFFFAOYSA-N
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一般描述
硼 叔 -丁胺络合物是一种温和的还原剂。它参与醛酮选择性还原为相应的醇。它作为还原剂参与合成单分散钯纳米粒子 (Pd NPs)、 单分散金 (Au) 纳米粒子和碳负载钯电催化剂。
应用
反应物涉及：
- 印度绘画的无损分析与保护处理
- 钌双齿膦配合物 或钌/铱双（ N -杂环卡宾）配合物介导的脱氢反应
- σ-硼烷复合物的形成
- 胺-硼烷加合物的乙醇解反应形成末端烯烃转移加氢还原系统
- 单壁碳纳米管的光化学硼氢化和氧化
硼 叔 -丁胺 (BTB) 络合物可用作以下合成中的强效共还原剂：
- 氧化铜纳米颗粒
- 双膦保护的金纳米簇
- 4-乙酰氧基肉桂醇
警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
John M Pettibone et al.
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We identify the reaction network governing gold monolayer protected cluster (MPC) formation during the reduction of Au(PPh(3))Cl and L(5) (L(5) = 1,5-bis(diphenylphosphino)pentane) in solutions. UV-vis spectroscopy and electrospray ionization mass spectrometry (ESI-MS) monitored the formation of ligated Au(x): 6 ≤
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Journal of nanoscience and nanotechnology, 13(9), 6027-6032 (2013-11-12)
To control the optical properties of Cu2O for a variety of application, we synthesized Cu2O in nanoscale without other treatments. Cu2O nanoparticles with an average size of 2.7 nm (sigma < or = 3.7%) were successfully synthesized in this study
A facile synthesis of monodisperse Au nanoparticles and their catalysis of CO oxidation.
Peng S, et al.
Nano Research, 1(3), 229-234 (2008)
Facile synthesis of 4-hydroxycinnamyl p-coumarates.
Lu C and Raplph J.
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Supported core@ shell electrocatalysts for fuel cells: close encounter with reality.
Hwang SJ, et al.
Scientific Reports, 3 (2013)
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