质量水平
检测方案
97%
形式
liquid
折射率
n20/D 1.509 (lit.)
bp
111-112 °C/18 mmHg (lit.)
密度
1.078 g/mL at 25 °C (lit.)
SMILES字符串
CC(=O)C1CCCCC1=O
InChI
1S/C8H12O2/c1-6(9)7-4-2-3-5-8(7)10/h7H,2-5H2,1H3
InChI key
OEKATORRSPXJHE-UHFFFAOYSA-N
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一般描述
已经研究了2-乙酰基环己酮（ACHE）在水中的酮-烯醇互变异构现象。
应用
2-乙酰环己酮被用于合成苯氨基乙醇胺。
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
Emilia Iglesias
The Journal of organic chemistry, 68(7), 2689-2697 (2003-03-29)
The kinetic study of the nitrosation of the enol of 2-acetylcyclohexanone (ACHE) has been performed in aqueous acid media in the absence and presence of alpha- and beta-cyclodextrin. The reaction is first-order with respect to both reactants concentration: [nitrite] and
Cédric Bouteiller et al.
Organic & biomolecular chemistry, 8(5), 1111-1120 (2010-02-19)
An operationally simple and concise synthesis of anilinoethanolamines, as NMDA NR2B receptor antagonist ifenprodil analogues, was developed via a copper-catalyzed amination of the corresponding bromoarene. Coupling was achieved with linear primary alkylamines, alpha,omega-diamines, hexanolamine and benzophenone imine, as well as
Emilia Iglesias
The Journal of organic chemistry, 68(7), 2680-2688 (2003-03-29)
The keto-enol tautomerism of 2-acetylcyclohexanone (ACHE) was studied in water under different experimental conditions. By contrast with other previously studied beta-diketones, the keto-enol interconversion in the ACHE system is a slow process. Under equilibrium conditions, the analysis of the absorbance
An alternative to the classical α-arylation: the transfer of an intact 2-iodoaryl from ArI(O₂CCF₃)₂.
Zhiyu Jia et al.
Angewandte Chemie (International ed. in English), 53(42), 11298-11301 (2014-09-10)
The α-arylation of carbonyl compounds is generally accomplished under basic conditions, both under metal catalysis and via aryl transfer from the diaryl λ(3)-iodanes. Here, we describe an alternative metal-free α-arylation using ArI(O2CCF3)2 as the source of a 2-iodoaryl group. The
Yoshihide Usami et al.
Molecules (Basel, Switzerland), 25(20) (2020-10-16)
Alkylamino coupling reactions at the C4 positions of 4-halo-1H-1-tritylpyrazoles were investigated using palladium or copper catalysts. The Pd(dba)2 catalyzed C-N coupling reaction of aryl- or alkylamines, lacking a β-hydrogen atom, proceeded smoothly using tBuDavePhos as a ligand. As a substrate
商品
Buchwald phosphine ligands for C-C, C-N, and C-O bond formation.
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