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Merck
CN

177970

Sigma-Aldrich

吡啶-d5

"100%", ≥99.96 atom % D

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别名:
氘代吡啶
经验公式(希尔记法):
C5D5N
CAS号:
分子量:
84.13
Beilstein:
114377
EC 号:
MDL编号:
UNSPSC代码:
12142201
eCl@ss:
39151701
PubChem化学物质编号:
NACRES:
NA.11

质量水平

同位素纯度

≥99.96 atom % D

检测方案

≥99% (CP)

形式

liquid

expl. lim.

0.34-6.3 % (lit.)

技术

NMR: suitable

杂质

≤0.05% water
water

折射率

n20/D 1.506 (lit.)

pH值(酸碱度)

8.5 (0.2 g/L)

bp

114.4 °C (lit.)

mp

-41 °C (lit.)

密度

1.05 g/mL at 25 °C (lit.)

质量偏移

M+5

SMILES字符串

[2H]c1nc([2H])c([2H])c([2H])c1[2H]

InChI

1S/C5H5N/c1-2-4-6-5-3-1/h1-5H/i1D,2D,3D,4D,5D

InChI key

JUJWROOIHBZHMG-RALIUCGRSA-N

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一般描述

Pyridine-d5 is a deuterated form of pyridine having an isotopic purity of 99.96atom%D. It is 100% isotopically enriched NMR (Nuclear Magnetic Resonance) solvent. It is widely employed for high resolution NMR studies due to its high chemical and isotopic purity. The reaction between pyridine vapor and heavy water in the presence of a palladium catalyst has been reported to afford pyridine-d5. Infrared (IR), Raman (in the range 300-4000cm-1) and high-resolution (0.06cm-1) FT-IR (Fourier transform infrared) spectral studies of pyridine-d5 have been reported.

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象形图

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警示用语:

Danger

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2

WGK

WGK 2

闪点(°F)

62.6 °F

闪点(°C)

17 °C

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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Vibrational spectra of C2v deuterium substituted pyridines. 4-pyridine-2, 3, 5, 6-d4 and pyridine-d5.
Stidham HD and Dilella DP.
Journal of Raman Spectroscopy, 9(4), 247-256 (1980)
The FT-IR spectra of pyridine and pyridine-d51.
Wong KN and Colson SD.
Journal of Molecular Spectroscopy, 104(1), 129-151 (1984)
Indra Prakash et al.
Natural product communications, 9(8), 1135-1138 (2014-09-23)
We report the isolation and complete structure of an isomer of rebaudioside D, known as rebaudioside D2. This novel steviol glycoside was isolated from a bioconversion reaction of rebaudioside A to rebaudioside D. Rebaudioside D2 possesses a relatively rare 1
Xu Pang et al.
Steroids, 93, 68-76 (2014-12-03)
For the first time, a systematic phytochemical study was performed on the roots of Marsdenia tenacissima. Finally, sixteen new polyoxypregnane glycosides, marstenacissides A1-A7 (1-7) and marstenacissides B1-B9 (8-16), were isolated from M. tenacissima roots. The structures of these new compounds
Xu Pang et al.
Carbohydrate research, 402, 236-240 (2014-12-17)
Five new steroidal saponins (1-5) were isolated from the fermentation broth of total furostanol glycosides from tubers of Dioscorea zingiberensis C.H. Wright incubated with a fungal, Absidia coerulea AS 3.3389, along with known saponins, zingiberensis new saponin (6), deltonin (7)

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