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Dear Customer:

The current international situation is complex and volatile, and uncertain tariff policies may potentially impact our product prices. Given these uncertainties, we value your understanding regarding order-related matters.

If you decide to place an order during this period, we reserve the right to adjust the price based on the evolving situation. We understand that market changes may cause inconvenience. We will negotiate with you if there’s a significant price fluctuation due to tariff policy changes before the order’s actual delivery, and in such cases we may adjust or cancel the order as necessary.

Merck
CN
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177261

Sigma-Aldrich

DPPF

greener alternative

97%

别名:

1,1′-二茂铁二基-双(二苯基膦), dppf

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About This Item

经验公式（希尔记法）:
C34H28FeP2
CAS号:
12150-46-8
分子量:
554.38
MDL编号:
MFCD00001422
UNSPSC代码:
12350000
PubChem化学物质编号:
24850625
NACRES:
NA.22
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质量水平

200

方案

97%

表单

powder

反应适用性

reaction type: Cross Couplings
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Carbonylations
reagent type: ligand
reaction type: Ene Reaction
reagent type: ligand
reaction type: Heck Reaction
reagent type: ligand
reaction type: Negishi Coupling
reagent type: ligand
reaction type: Sonogashira Coupling
reagent type: ligand
reaction type: Stille Coupling
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Tsuji-Trost Reaction

环保替代产品特性

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

181-182 °C (dec.) (lit.)

官能团

phosphine

环保替代产品分类

Aligned,

SMILES字符串

[Fe].[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6

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1 of 4

此商品
F0152F0402F0527
Nalgene® baffled shake flask flask capacity 500 mL, Straight neck

F0277

Nalgene® baffled shake flask

Nalgene® baffled shake flask flask capacity 250 mL, Beaded neck

F0152

Nalgene® baffled shake flask

Nalgene® baffled shake flask flask capacity 1,000 mL, Straight neck

F0402

Nalgene® baffled shake flask

Nalgene® baffled shake flask capacity 2,000 mL, Beaded neck

F0527

Nalgene® baffled shake flask

manufacturer/tradename

Nalgene® 4110-0500

manufacturer/tradename

Nalgene® 4110-0250

manufacturer/tradename

Nalgene® 4110-1000

manufacturer/tradename

Nalgene® 4110-2000

material

straight neck transparent polycarbonate flask

material

beaded neck transparent polycarbonate flask

material

straight neck transparent polycarbonate flask

material

beaded neck translucent polycarbonate flask, transparent polycarbonate

sterility

non-sterile

sterility

non-sterile

sterility

non-sterile

sterility

non-sterile

feature

graduations 50 mL (Marked every 25mL at 400 - 500mL range), without cap

feature

cap: no, graduations 25 mL, without cap

feature

without cap

feature

graduations 200 mL, without cap

packaging

case of 4

packaging

case of 4

packaging

case of 2 ea

packaging

case of 2

一般描述

我们致力于为您提供更环保的替代产品，以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型，提高了催化效率。点击此处了解更多详情。
通过Pd-膦依序形成C-C和C-O键，制备新型官能化呋喃衍生物。[1]

应用

Pd(II)-催化交叉偶联合成奥氮平环系统的配体。[2]
可作为从胺和酒精绿色合成胺的钌催化借氢反应的配体。

借氢反应法钌催化胺和磺酰胺N-烷基化

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

    • 历史批次信息供参考:

    分析证书(COA)

    Lot/Batch Number
    0000424006
    0000424006
    0000398133
    0000398133
    0000262681

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    Alejandro Pérez Luna et al.
    Organic letters, 5(25), 4771-4774 (2003-12-05)
    The diastereoselective synthesis of hydrazinocyclopentenes 6 or 7 can be achieved in a straightforward manner from Diels-Alder adduct 4 using an acid-catalyzed rearrangement or a palladium-catalyzed allylic substitution reaction. In the latter case, enantioenriched compounds with ee values up to
    Wolfe, J. P.; Buchwald, S. L.
    Journal of the American Chemical Society, 119, 6054-6054 (1997)
    Anastasia, L.; Dumond, Y. R.; Negishi, E.
    European Journal of Organic Chemistry, 3039-3039 (2001)
    Tanimori, Shinji; et al.
    Synthesis, 5, 865-869 (2006)
    Driver, M. S.; Hartwig, J. F.
    Journal of the American Chemical Society, 118, 7217-7217 (1996)
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