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质量水平
方案
≥97%
表单
liquid
折射率
n20/D 1.396 (lit.)
沸点
61-62 °C (lit.)
密度
0.83 g/mL at 25 °C (lit.)
官能团
ether
储存温度
2-8°C
SMILES字符串
COCC#C
InChI
1S/C4H6O/c1-3-4-5-2/h1H,4H2,2H3
InChI key
YACFFSVYSPMSGS-UHFFFAOYSA-N
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一般描述
目前已研究了甲基炔丙基醚的拉曼光谱。
应用
甲基炔丙基醚用于合成[Ru3(μ3-κ(2)-HNNMe2)(μ3-κ(2)-MeOCH2CCH2)(μ-CO)2(CO)6]。
警示用语:
Danger
危险分类
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
补充剂危害
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
-0.4 °F - closed cup
闪点(°C)
-18 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves
法规信息
新产品
Chemistry (Weinheim an der Bergstrasse, Germany), 11(20), 6040-6052 (2005-07-30)
The reactions of the hydrido-triruthenium cluster complex [Ru3(mu-H)(mu3-kappa(2)-HNNMe2)(CO)9] (1; H2NNMe2 = 1,1-dimethylhydrazine) with alkynes that have alpha-hydrogen atoms give trinuclear derivatives containing edge-bridging allyl or face-capping alkenyl ligands. Under mild conditions (THF, 70 degrees C) the isolated products are as
Conformational stability, barriers to internal rotation, ab initio calculations and vibrational assignment of methyl propargyl ether.
Journal of Molecular Structure, 320, 193-216 (1994)
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