检测方案
97%
形式
liquid
折射率
n20/D 1.496 (lit.)
bp
103 °C (lit.)
密度
1.635 g/mL at 25 °C (lit.)
储存温度
−20°C
SMILES字符串
Brc1ccoc1
InChI
1S/C4H3BrO/c5-4-1-2-6-3-4/h1-3H
InChI key
LXWLEQZDXOQZGW-UHFFFAOYSA-N
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应用
3-溴呋喃用于制备 2-取代的 3-糠醛。它也用于 5,6-脱氢降冰片烷素的合成。
警示用语:
Danger
危险声明
危险分类
Flam. Liq. 2
WGK
WGK 3
闪点(°F)
37.4 °F
闪点(°C)
3 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Bioorganic chemistry, 31(1), 68-79 (2003-04-17)
Diels-Alder addition of furans (furan, furfuryl alcohol, and 3-bromofuran) to maelic anhydride yields three distinct 5,6-dehydronorcantharidins. Hydrogenation of (4,10-dioxatricyclo[5.2.1.0]decane-3,5-dione) (4a), in dry ethanol affords the monoester (7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic aid monoethyl ester) (6). Subsequent transesterification affords a series of monoesters (7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic acid
Journal of the American Chemical Society, 130(12), 4097-4104 (2008-03-05)
Furans and pyrroles are important synthons in chemical synthesis and are commonly found in natural products, pharmaceutical agents, and materials. Introduced herein are three methods to prepare 2-substituted 3-furfurals starting from 3-furfural, 3-bromofuran, and 3-vinylfurans. Addition of a variety of
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