175102
氟对亚磺酸
purified by triple-distillation
别名:
六氟对氨基磺酸, 六氟锑酸, 单氢六氟锑酸, 氟对亚磺酸
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关于此项目
线性分子式:
HF · SbF5
化学文摘社编号:
分子量:
236.76
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
241-023-8
MDL number:
Form:
liquid
产品名称
氟对亚磺酸, purified by triple-distillation
InChI key
MBAKFIZHTUAVJN-UHFFFAOYSA-I
InChI
1S/6FH.Sb/h6*1H;/q;;;;;;+5/p-5
SMILES string
F.F[Sb](F)(F)(F)F
vapor pressure
14 mmHg ( 18 °C)
form
liquid
purified by
triple-distillation
density
2.885 g/mL at 25 °C (lit.)
Quality Level
Application
HF/SbF5式制备亚烷基氧鎓盐的优良介质。
General description
HF/SbF5 可以通过混合氟化氢和氟化锑来合成。 氟锑酸(HF/SbF5)是SbF5和 HF的组合物。它是已知最强的液态超强酸。
Packaging
PFA/FEP 瓶封装
signalword
Danger
Hazard Classifications
Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1A
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Structure and vibrational spectra of H+ (HF) n (n= 2?9) clusters: An ab initio study.
Sophy KB and Kuo JL
J. Chem. Phys. , 131(22), 224307-224307 (2009)
Rolf Minkwitz et al.
Inorganic chemistry, 38(5), 844-847 (2001-10-24)
We have studied the preparation and isolation of the halogenated alkylidene oxonium salts CH(3)OCHX(+)MF(6)(-) (X = Cl, F; M = As, Sb). Addition of dichloromethylmethylether at -78 degrees C to the superacidic media HF/MF(5) resulted in the formation of the
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