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Merck
CN

175064

Sigma-Aldrich

亚硝四氟硼酸盐

95%

别名:

四氟硼酸亚硝

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About This Item

线性分子式:
NOBF4
CAS号:
分子量:
116.81
EC 号:
MDL编号:
UNSPSC代码:
12352101
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

95%

反应适用性

reagent type: oxidant

储存温度

2-8°C

SMILES字符串

N#[O+].F[B-](F)(F)F

InChI

1S/BF4.NO/c2-1(3,4)5;1-2/q-1;+1

InChI key

KGCNVGDHOSFKFT-UHFFFAOYSA-N

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应用

四氟硼酸亚硝盐是一种有效的亚硝化和重氮化剂。它与醇和仲胺反应,分别产生亚硝酸烷基酯和亚硝胺。它与伯胺反应,生成重氮四氟硼酸盐。NOBF4也是一种温和的氧化剂,常用于单电子转移氧化反应。

象形图

Corrosion

警示用语:

Danger

危险声明

危险分类

Skin Corr. 1B

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Electronically regulated thermally and light-gated electron transfer from anions to naphthalenediimides.
Guha, Samit et al.
Journal of the American Chemical Society, 133(39), 15256-15259 (2011)
S Mohr et al.
The Journal of biological chemistry, 274(14), 9427-9430 (1999-03-27)
S-Nitrosylation of protein thiol groups by nitric oxide (NO) is a widely recognized protein modification. In this study we show that nitrosonium tetrafluoroborate (BF4NO), a NO+ donor, modified the thiol groups of glyceraldehyde-3-phosphate dehydrogenase (GAPDH) by S-nitrosylation and caused enzyme
J Li et al.
Biochemical and biophysical research communications, 240(2), 419-424 (1997-12-06)
The caspases are a family of at least 10 human cysteine proteases that participate in cytokine maturation and in apoptotic signal transduction and execution mechanisms. Peptidic inhibitors of these enzymes are capable of blocking cytokine maturation and apoptosis, demonstrating their
S Mohr et al.
FEBS letters, 348(3), 223-227 (1994-07-18)
Previous studies have suggested that glyceraldehyde-3-phosphate dehydrogenase (GAPDH) undergoes covalent modification of an active site thiol by a NO.-induced [32P]NAD(+)-dependent mechanism. However, the efficacy of GAPDH modification induced by various NO donors was found to be independent of spontaneous rates
C Würth et al.
Nanoscale, 9(12), 4283-4294 (2017-03-16)
The rational design of brighter upconversion nanoparticles (UCNPs) requires a better understanding of the radiationless deactivation pathways in these materials. Here, we demonstrate the potential of excitation power density (P)-dependent studies of upconversion (UC) luminescence intensities, slope factors, and absolute

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