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Merck
CN

172626

Sigma-Aldrich

十二烷基三苯基溴化磷

98%

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About This Item

线性分子式:
CH3(CH2)11P(C6H5)3Br
CAS号:
分子量:
511.52
EC 号:
MDL编号:
UNSPSC代码:
12352002
PubChem化学物质编号:

方案

98%

反应适用性

reaction type: C-C Bond Formation

mp

85-88 °C (lit.)

SMILES字符串

[Br-].CCCCCCCCCCCC[P+](c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C30H40P.BrH/c1-2-3-4-5-6-7-8-9-10-20-27-31(28-21-14-11-15-22-28,29-23-16-12-17-24-29)30-25-18-13-19-26-30;/h11-19,21-26H,2-10,20,27H2,1H3;1H/q+1;/p-1

InChI key

NSIFOGPAKNSGNW-UHFFFAOYSA-M

应用

Involved in comparative electrochemical studies of anticorrosion efficiency of nanocomposite coatings

Intercalating agent for modifying anticorrosion, gas barrier, mechanical and thermal properties of nanocomposite coatings

Mediator for reactions of nitrophenyl acetate

Studies of:
  • Nucleophilic substitution kinetics of sulfonate ester
  • Intercalated polyester / silicate nanocomposites
  • Thermal stability of quaternary phosphonium-modified montmorillonites in silicate layered polymer nanocomposites

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Ben C Chung et al.
Science (New York, N.Y.), 341(6149), 1012-1016 (2013-08-31)
MraY (phospho-MurNAc-pentapeptide translocase) is an integral membrane enzyme that catalyzes an essential step of bacterial cell wall biosynthesis: the transfer of the peptidoglycan precursor phospho-MurNAc-pentapeptide to the lipid carrier undecaprenyl phosphate. MraY has long been considered a promising target for
Meera Shanmuganathan et al.
Analytica chimica acta, 773, 24-36 (2013-04-09)
High quality assays are needed in drug discovery to reduce the high attrition rate of lead compounds during primary screening. Capillary electrophoresis (CE) represents a versatile micro-separation technique for resolution of enzyme-catalyzed reactions, including substrate(s), product(s), cofactor(s) and their stereoisomers
Yuzuru Itoh et al.
Science (New York, N.Y.), 340(6128), 75-78 (2013-04-06)
The 21st amino acid, selenocysteine (Sec), is synthesized on its cognate transfer RNA (tRNA(Sec)). In bacteria, SelA synthesizes Sec from Ser-tRNA(Sec), whereas in archaea and eukaryotes SepSecS forms Sec from phosphoserine (Sep) acylated to tRNA(Sec). We determined the crystal structures
Lisa M Willis et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(51), 20753-20758 (2013-12-05)
Capsular polysaccharides (CPSs) are high-molecular-mass cell-surface polysaccharides, that act as important virulence factors for many pathogenic bacteria. Several clinically important Gram-negative pathogens share similar systems for CPS biosynthesis and export; examples include Escherichia coli, Campylobacter jejuni, Haemophilus influenzae, Neisseria meningitidis
Livia Regina Manzine et al.
FEBS letters, 587(7), 906-911 (2013-02-23)
In bacteria selenocysteyl-tRNA(sec) (SelC) is synthesized by selenocysteine synthase (SelA). Here we show by fluorescence anisotropy binding assays and electron microscopical symmetry analysis that the SelA-tRNA(sec) binding stoichiometry is of one tRNA(sec) molecule per SelA monomer (1:1) rather than the

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