推荐产品
质量水平
方案
99%
表单
liquid
折射率
n20/D 1.408 (lit.)
沸点
103-105 °C (lit.)
密度
0.945 g/mL at 25 °C (lit.)
官能团
ester
SMILES字符串
COC(=O)C#C
InChI
1S/C4H4O2/c1-3-4(5)6-2/h1H,2H3
InChI key
IMAKHNTVDGLIRY-UHFFFAOYSA-N
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应用
尿苷和胸苷的N-3保护剂。
丙酸甲酯被用于合成多取代的 3-芳基氨基丙烯酸酯和四氢嘧啶-2-酮衍生物 。也用作毛细管电泳的巯基衍生剂 。
在三苯基膦促进的一锅、四组分反应中用于合成1,2,3,5-苯四羧酸。
警示用语：
Danger
危险分类
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
60.8 °F - closed cup
闪点(°C)
16 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Li-Li Zhang et al.
Molecular diversity, 18(1), 79-89 (2014-01-31)
Polysubstituted 3-arylaminoacrylate and tetrahydropyrimidin-2-one derivatives could be selectively produced from the one-pot domino reaction of arylamines, methyl propiolate, aromatic aldehydes, and urea in ethanol in the presence of FeCl3 as catalyst. Under similar reactions secondary amines such as morpholine and
Tetrahedron Letters, 36, 3261-3261 (1995)
Eirini-Chrysanthi Tsardaka et al.
Journal of chromatography. A, 1300, 204-208 (2013-06-04)
In this study we demonstrate - for the first time - the suitability of methyl propiolate - an alkylester of propiolic acid - as a thiol derivatizing reagent for capillary electrophoresis. Glutathione (as analyte in yeast samples) and N-acetylcysteine (as
Graziella Tocco et al.
Journal of agricultural and food chemistry, 68(40), 11088-11095 (2020-09-15)
The present study reports on the powerful nematicidal activity of a series of electron-deficient alkynes against the root-knot nematode Meloidogyne incognita (Kofoid and White) Chitwood. Interestingly, we found that the conjugation of electron-withdrawing carbonyl groups to an alkyne triple bond
Helvetica Chimica Acta, 89, 2918-2918 (2006)
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