171441
三氟碘甲烷
99%
别名:
三氟甲基碘, 全氟甲基碘, 碘代三氟甲烷
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关于此项目
经验公式（希尔记法）:
CF3I
化学文摘社编号:
分子量:
195.91
UNSPSC Code:
12142100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
219-014-5
Beilstein/REAXYS Number:
1732740
MDL number:
Application
用于 α,ß-不饱和酮的铑催化 α-三氟甲基化反应的试剂。
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Legal Information
Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC
signalword
Warning
hcodes
Hazard Classifications
Muta. 2 - Ozone 1 - Press. Gas Compr. Gas
存储类别
2A - Gases
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves
法规信息
新产品
此项目有
C Stefan Lehmann et al.
Faraday discussions, 153, 173-187 (2011-01-01)
The control of multichannel ionic fragmentation dynamics in CF3I is studied by femtosecond pulse shaping and velocity map photoelectron photoion coincidence imaging. When CF3I is photoexcited with femtosecond laser pulses around 540 nm there are two major ions observed in
Natalia B Shustova et al.
Journal of the American Chemical Society, 128(49), 15793-15798 (2006-12-07)
Reaction of a mixture of insoluble higher fullerenes with CF3I at 500 degrees C produced a single abundant isomer of C74(CF3)12, C76(CF3)12, and C80(CF3)12, two abundant isomers of C78(CF3)12 and C82(CF3)12, and an indeterminant number of isomers of C84(CF3)12. Using
G Hancock et al.
Physical chemistry chemical physics : PCCP, 9(18), 2234-2239 (2007-05-10)
Frequency modulated diode laser based absorption at 1.315 microm has been used to measure the Doppler lineshapes of the I((2)P(1/2)-(2)P(3/2)) transition in atomic iodine produced from the 266 nm photolysis of both CF(3)I and C(2)F(5)I. Wavelength resolved laser gain is
A Vinegar et al.
Inhalation toxicology, 12(8), 751-763 (2000-07-06)
Most proposed replacements for Halon 1301 as a fire suppressant are halogenated hydrocarbons. The acute toxic endpoint of concern for these agents is cardiac sensitization. An approach is described that links the cardiac endpoint as assessed in dogs to a
D E Dodd et al.
Inhalation toxicology, 11(11), 1041-1055 (1999-11-24)
CF(3)I is being considered by the U.S. Air Force as a replacement for Halon 1301 for fire-extinguishing requirements in unoccupied spaces. The purpose of this study was to determine and evaluate the potential for CF(3)I to produce reproductive toxicity and
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In 2001, Professor William Dolbier, Jr., at the University of Florida reported1 an approach to nucleophilic trifluoromethylation based on the generation of a trifluoromethyl anion using CF3I in the presence of a powerful twoelectron reductant, tetrakis(dimethylamino)ethylene (TDAE)
在2001年，佛罗里达大学的William Dolbier，Jr.教授报告了一种亲核三氟甲基化的方法，该方法基于在强力双电子还原剂四（二甲基氨基）乙烯（TDAE）存在下使用CF3I生成三氟甲基阴离子。
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