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Merck
CN

171441

Sigma-Aldrich

三氟碘甲烷

99%

别名:

三氟甲基碘, 全氟甲基碘, 碘代三氟甲烷

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About This Item

经验公式(希尔记法):
CF3I
CAS号:
分子量:
195.91
Beilstein:
1732740
EC 号:
MDL编号:
UNSPSC代码:
12142100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

99%

bp

−22.5 °C (lit.)

mp

<−78 °C (lit.)

SMILES字符串

FC(F)(F)I

InChI

1S/CF3I/c2-1(3,4)5

InChI key

VPAYJEUHKVESSD-UHFFFAOYSA-N

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应用

用于 α,ß-不饱和酮的铑催化 α-三氟甲基化反应的试剂。

包装

以Sure/Pac 气瓶供货,并具有配备 1/4" NPTF出口外螺纹的青铜针阀。使用样品筒之前,确保关闭阀门,然后拆下密封出气阀的镀锌钢六角帽。

与以下装置兼容:

法律信息

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC

调节阀

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警示用语:

Warning

危险声明

危险分类

Muta. 2 - Ozone 1 - Press. Gas Compr. Gas

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves

法规信息

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Discovering and verifying elusive fullerene cage isomers: structures of C2-p11-(C74-D3h)(CF3)12 and C2-p11-(C(78)-D3h5)(CF3)12.
Natalia B Shustova et al.
Angewandte Chemie (International ed. in English), 46(22), 4111-4114 (2007-04-25)
D E Dodd et al.
Fundamental and applied toxicology : official journal of the Society of Toxicology, 35(1), 64-77 (1997-01-01)
Trifluoroiodomethane (CF3I) is being considered as a replacement compound for halon fire suppressants. Its structure is similar to that of Halon 1301 (CF3Br), but it has very low ozone depletion potential compared to CF3Br. As part of the process of
C Stefan Lehmann et al.
Faraday discussions, 153, 173-187 (2011-01-01)
The control of multichannel ionic fragmentation dynamics in CF3I is studied by femtosecond pulse shaping and velocity map photoelectron photoion coincidence imaging. When CF3I is photoexcited with femtosecond laser pulses around 540 nm there are two major ions observed in
D E Dodd et al.
Inhalation toxicology, 11(11), 1041-1055 (1999-11-24)
CF(3)I is being considered by the U.S. Air Force as a replacement for Halon 1301 for fire-extinguishing requirements in unoccupied spaces. The purpose of this study was to determine and evaluate the potential for CF(3)I to produce reproductive toxicity and
Karlee P Castro et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(59), 13547-13565 (2019-08-06)
A solution, solid-state, and computational study is reported of polycyclic aromatic hydrocarbon PAH/PAH(CF3 )n donor/acceptor (D/A) charge-transfer complexes that involve six PAH(CF3 )n acceptors with known gas-phase electron affinities that range from 2.11(2) to 2.805(15) eV and four PAH donors, including

商品

In 2001, Professor William Dolbier, Jr., at the University of Florida reported1 an approach to nucleophilic trifluoromethylation based on the generation of a trifluoromethyl anion using CF3I in the presence of a powerful twoelectron reductant, tetrakis(dimethylamino)ethylene (TDAE)

在2001年,佛罗里达大学的William Dolbier,Jr.教授报告了一种亲核三氟甲基化的方法,该方法基于在强力双电子还原剂四(二甲基氨基)乙烯(TDAE)存在下使用CF3I生成三氟甲基阴离子。

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