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Merck
CN
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文件

安全信息

167940

Sigma-Aldrich

巴豆酸乙酯

99%

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线性分子式:
CH3CH=CHCOOC2H5
分子量:
114.14
Beilstein:
635834
EC 号:
210-808-7
MDL编号:
MFCD00009289
UNSPSC代码:
12352100
PubChem化学物质编号:
24850227
NACRES:
NA.22

蒸汽密度

3.9 (vs air)

检测方案

99%

形式

liquid

折射率

n20/D 1.424 (lit.)

bp

142-143 °C (lit.)

密度

0.918 g/mL at 25 °C (lit.)

SMILES字符串

CCOC(=O)\C=C\C

InChI

1S/C6H10O2/c1-3-5-6(7)8-4-2/h3,5H,4H2,1-2H3/b5-3+

InChI key

ZFDIRQKJPRINOQ-HWKANZROSA-N

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一般描述

巴豆酸乙酯在硼氢化作用下生成 2-氚化 3-羟基丁酸 。

应用

巴豆酸乙酯用于 (+/-)-蝙蝠葛酸的全合成 。它也被用于 3-甲基-4-氧代辛酸乙酯的合成 。

象形图

FlameExclamation mark
GHS02,GHS07

警示用语：

Danger

危险声明

H225,H319

危险分类

Eye Irrit. 2 - Flam. Liq. 2

WGK

WGK 2

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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Synthesis of all stereoisomers of cognac lactones via microbial reduction and enzymatic resolution strategies.
Benedetti F, et al.
Tetrahedron Asymmetry, 12(3), 505-511 (2001)
P Willadsen et al.
European journal of biochemistry, 54(1), 247-252 (1975-05-01)
1. A specimen of stereospecifically 2-tritiated 3-hydroxybutyric acid was prepared by hydroboration of ethyl crotonate. It was assumed that the hydroboration reaction took a syn course and hence that (2R,3S) plus (2S,3R)-3-hydroxy[2 minus 3H1]butyric acid was formed after oxidation and
Hongjuan Hu et al.
The Journal of organic chemistry, 69(11), 3782-3786 (2004-05-22)
A modular and concise total synthesis of (+/-)-daurichromenic acid has been accomplished in four steps from ethyl acetoacetate, ethyl crotonate, and trans,trans-farnesal. A series of analogues of this natural product, which has potent anti-HIV activity, were also prepared from ethyl
Amélie Slegers et al.
Molecules (Basel, Switzerland), 20(6), 10980-11016 (2015-06-18)
Developed from crosses between Vitis vinifera and North American Vitis species, interspecific hybrid grape varieties are becoming economically significant in northern areas, where they are now extensively grown for wine production. However, the varietal differences between interspecific hybrids are not

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