质量水平
检测方案
95%
包含
~0.1% Drapex 39 as stabilizer
杂质
~5% 1,1-dichloroacetone and/or mesityl oxide
折射率
n20/D 1.432 (lit.)
bp
120 °C (lit.)
mp
−44.5 °C
溶解性
alcohol: miscible
chloroform: miscible
diethyl ether: miscible
密度
1.162 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
CC(=O)CCl
InChI
1S/C3H5ClO/c1-3(5)2-4/h2H2,1H3
InChI key
BULLHNJGPPOUOX-UHFFFAOYSA-N
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一般描述
Direct aldol reaction of chloroacetone with of 4-nitrobenzaldehyde catalyzed by L-proline amides has been investigated.
应用
Chloroacetone was used in the synthesis of double-chain nonionic surfactants with an acid decomposition function via acid-catalyzed condensation with fatty alcohols (octyl, decyl and dodecyl). It was also used in the synthesis of meso-tetramethyl tetrakis-(4-phenoxy acetone)calix[4]pyrrole.
警示用语：
Danger
危险分类
Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
95.0 °F
闪点(°C)
35 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
L-Proline amide-catalyzed direct asymmetric aldol reaction of aldehydes with chloroacetone.
He L, et al.
Tetrahedron, 62(2), 346-351 (2006)
Angela F Danil de Namor et al.
Physical chemistry chemical physics : PCCP, 12(3), 753-760 (2010-01-13)
Following the synthesis and characterization of meso-tetramethyl tetrakis (4-phenoxy acetone) calix[4]pyrrole, 1, the solution properties of this receptor in various solvents were investigated. Particular emphasis is placed on the selection of the solvent in assessing thermodynamic selectivity in ion complexation
Luis F Garcia-Alles et al.
Biochemistry, 43(41), 13037-13045 (2004-10-13)
Dihydroxyacetone (Dha) kinases are a sequence-conserved family of enzymes, which utilize two different phosphoryldonors, ATP in animals, plants, and some bacteria, and a multiphosphoprotein of the phosphoenolpyruvate carbohydrate phosphotransferase system (PTS) in most bacteria. Here, we compare the PTS-dependent kinase
H Lauble et al.
Acta crystallographica. Section D, Biological crystallography, 57(Pt 2), 194-200 (2001-02-15)
The crystal structures of hydroxynitrile lyase from Manihot esculenta (MeHNL) complexed with the native substrate acetone and substrate analogue chloroacetone have been determined and refined at 2.2 A resolution. The substrates are positioned in the active site by hydrogen-bond interactions
M R Hollaway et al.
The Biochemical journal, 191(3), 811-826 (1980-12-01)
1. Chloroacetone (I) was shown to be an active-site-directed inhibitor of the aliphatic amidase (EC 3.5.1.4) from Pseudomonas aeruginosa strain PAC142.2. This inhibitor reacted with the enzyme in two stages: the first involving the reversible formation of an enzymically inactive
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