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质量水平
方案
98%
表单
solid
mp
105-108 °C (lit.)
官能团
amine
SMILES字符串
CC(C)(C)OC(N)=O
InChI
1S/C5H11NO2/c1-5(2,3)8-4(6)7/h1-3H3,(H2,6,7)
InChI key
LFKDJXLFVYVEFG-UHFFFAOYSA-N
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一般描述
氨基甲酸 叔丁酯与各种芳基（Het）卤化物的钯催化交叉偶联反应已被研究，其中Cs2CO3 作为1,4-二恶烷（溶剂）中的碱。
应用
氨基甲酸叔丁酯被用于 N-Boc保护的苯胺钯催化合成。它被用于合成四取代吡咯，在C-3位以酯或酮基官能化。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Maximilian Tromayer et al.
Polymer chemistry, 8(2), 451-460 (2017-03-07)
The possibility of the direct encapsulation of living cells
One-Pot Three-Component Synthesis of Tetrasubstituted NH Pyrroles from Secondary Propargylic Alcohols, 1, 3-Dicarbonyl Compounds and tert-Butyl Carbamate.
Cadierno V, et al.
Journal of Heterocyclic Chemistry, 47(1), 233-236 (2010)
Pd-catalyzed amidation of aryl (Het) halides with< i> tert</i>-butyl carbamate.
Qin L, et al.
Tetrahedron Letters, 51(33), 4446-4448 (2010)
Swapna Bhagwanth et al.
The Journal of organic chemistry, 74(12), 4634-4637 (2009-06-13)
The scope of Pd-catalyzed synthesis of N-Boc-protected anilines from aryl bromides and commercially available tert-butyl carbamate is described. For the first time, this process can be conducted at room temperature (17-22 degrees C) using a combination of Pd(2)dba(3).CHCl(3) and a
Tetsuo Cai et al.
The Journal of neuroscience : the official journal of the Society for Neuroscience, 39(43), 8600-8610 (2019-09-19)
γ-Secretase is an intramembrane-cleaving protease that generates the toxic species of the amyloid-β peptide (Aβ) that is responsible for the pathology of Alzheimer disease. The catalytic subunit of γ-secretase is presenilin 1 (PS1), which is a polytopic membrane protein with
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