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Merck
CN

167169

Sigma-Aldrich

3-溴-1-丙醇

97%

别名:

三甲烯溴醇

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About This Item

线性分子式:
Br(CH2)3OH
CAS号:
分子量:
138.99
Beilstein:
969160
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

97%

表单

liquid

折射率

n20/D 1.488 (lit.)

沸点

62 °C/5 mmHg (lit.)

密度

1.537 g/mL at 25 °C (lit.)

官能团

bromo
hydroxyl

储存温度

2-8°C

SMILES字符串

OCCCBr

InChI

1S/C3H7BrO/c4-2-1-3-5/h5H,1-3H2

InChI key

RQFUZUMFPRMVDX-UHFFFAOYSA-N

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一般描述

在胶束介质和阳离子或非离子表面活性剂微乳液中,研究了 3-溴-1-丙醇、苯酚和一系列取代苯酚的反应

3-溴-1-丙醇是一种亲电子试剂,可在亲核取代反应和氧化还原聚合反应中作为底物。

应用

3-溴-1-丙醇被用于合成对荧光卤素敏感的喹啉类染料和熔融盐聚合物 。它被用于通过季铵氨基酸环化合成手性、季铵脯氨酸
最近用作斯文氧化法合成绿色试剂的接枝剂

象形图

CorrosionExclamation mark

警示用语:

Danger

危险声明

危险分类

Acute Tox. 4 Oral - Eye Dam. 1

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

149.0 °F - closed cup

闪点(°C)

65 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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分析证书(COA)

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Fredrik Currie
Journal of colloid and interface science, 277(1), 230-234 (2004-07-28)
The reaction between 3-bromo-1-propanol and phenol and a series of phenols carrying substituents in 4-position was studied in micellar media and in microemulsions based on either a cationic or a nonionic surfactant. The reactivity and the yield were evaluated and
Takeo Kawabata et al.
Journal of the American Chemical Society, 128(48), 15394-15395 (2006-11-30)
An enantiodivergent asymmetric cyclization of N-Boc-N-omega-bromoalkyl-alpha-amino acid derivatives has been developed. With potassium amide bases in DMF, cyclization proceeds with retention of configuration, while inversion of configuration was observed with lithium amide bases in THF. Chirality of the parent amino
Wei Song et al.
Molecules (Basel, Switzerland), 25(17) (2020-08-23)
Azobenzene (AB) units were successfully introduced into poly(1,6-heptadiyne)s in order to ensure smooth synthesis of double- and single-stranded poly(1,6-heptadiyne)s (P1 and P2) and simultaneously realize the self-assembly by Grubbs-III catalyst-mediated metathesis cyclopolymerization (CP) of AB-functionalized bis(1,6-heptadiyne) and 1,6-heptadiyne monomers (M1
Synthesis of molten salt-type polymer brush and effect of brush structure on the ionic conductivity.
Yoshizawa M and Ohno H.
Electrochimica Acta, 46(10), 1723-1728 (2001)
Use of self-assembled surfactant systems as media for a substitution reaction
Fredrik and Currie
Journal of Colloid and Interface Science, 277, 230-234 (2004)

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