产品名称
1-溴-4-硝基苯, 99%
InChI key
ZDFBKZUDCQQKAC-UHFFFAOYSA-N
InChI
1S/C6H4BrNO2/c7-5-1-3-6(4-2-5)8(9)10/h1-4H
SMILES string
[O-][N+](=O)c1ccc(Br)cc1
assay
99%
form
solid
bp
255-256 °C (lit.)
mp
124-126 °C (lit.)
functional group
bromo
nitro
Quality Level
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General description
用循环伏安法研究了 1-溴-4-硝基苯在离子液体中锌微电极上的电化学还原 。1-溴-4-硝基苯与呋喃-2-基三丁基锡(以 Dabco(三乙二胺)为配体)发生钯催化的斯蒂尔交叉偶联反应 。它与 p -甲酚反应生成 1-甲基-4-(4-硝基苯氧基)苯 。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
危险化学品
此项目有
Evgeniy G Gordeev et al.
PloS one, 13(6), e0198370-e0198370 (2018-06-08)
Additive manufacturing with fused deposition modeling (FDM) is currently optimized for a wide range of research and commercial applications. The major disadvantage of FDM-created products is their low quality and structural defects (porosity), which impose an obstacle to utilizing them
Jin-Heng Li et al.
The Journal of organic chemistry, 70(7), 2832-2834 (2005-03-25)
[reaction: see text] An efficient Pd(OAc)2/Dabco-catalyzed Stille cross-coupling reaction procedure has been developed. In the presence of Pd(OAc)2 and Dabco (triethylenediamine), various aryl halides including aryl iodides, aryl bromides, and activated aryl chlorides were coupled efficiently with organotin compounds to
Sven Ernst et al.
Physical chemistry chemical physics : PCCP, 16(10), 4478-4482 (2014-01-30)
The electrochemical reduction of 1-bromo-4-nitrobenzene (p-BrC6H4NO2) at zinc microelectrodes in the [C4mPyrr][NTf2] ionic liquid was investigated via cyclic voltammetry. The reduction was found to occur via an EC type mechanism, where p-BrC6H4NO2 is first reduced by one electron, quasi-reversibly, to
Synthesis of diaryl ethers using an easy-to-prepare, air-stable, soluble copper (I) catalyst.
Gujadhur R and Venkataraman D.
Synthetic Communications, 31(18), 2865-2879 (2001)
Xiao Yan et al.
Physical chemistry chemical physics : PCCP, 22(11), 6222-6230 (2020-03-05)
Unveiling the reaction mechanism is significant for developing high-performance catalysts. In this paper, a series of precisely controlled PdxM147-x (M = Cu, Pt, Au, Rh, Ru) dendrimer encapsulated nanoparticles (DENs) has been successfully synthesized. The mechanisms of PdxM147-x as catalysts
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