检测方案
96%
形式
liquid
折射率
n20/D 1.440 (lit.)
bp
250 °C (lit.)
密度
1.113 g/mL at 25 °C (lit.)
SMILES字符串
CCOC(=O)CC(=O)CC(=O)OCC
InChI
1S/C9H14O5/c1-3-13-8(11)5-7(10)6-9(12)14-4-2/h3-6H2,1-2H3
InChI key
ZSANYRMTSBBUCA-UHFFFAOYSA-N
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应用
1,3-丙酮二羧酸二乙酯已被用于合成新型吡啶并[4,3,2-de]喹啉、异喹啉并[6,5,4,3-cde]喹啉和吡唑啉。它已在(±)-硫霉素这种强力β-内酰胺抗生素的合成中用作起始试剂。
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
法规信息
新产品
Anti-cancer drug design, 15(2), 99-108 (2000-07-20)
A series of novel pyrido[4,3,2-de]quinoline and isoquinolino[6,5,4,3-cde] quinoline compounds was synthesized and evaluated for cytotoxicity in the National Cancer Institute developmental therapeutics program. The tricyclic compound 7 was synthesized by the cyclization of 3,4-diamino-1,2dimethoxybenzene with diethyl 1,3-acetonedicarboxylate. Oxidation of monochloropyrido[4,3,2-de]quinoline
A synthesis of the pyrazomycins.
The Journal of organic chemistry, 41(2), 287-290 (1976-01-23)
A practical synthesis of (?)-thienamycin.
Tetrahedron Letters, 21(29), 2783-2786 (1980)
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