所有图片(2)
About This Item
线性分子式:
BrCH2CH=CHCOOCH3
CAS号:
分子量:
179.01
Beilstein:
1745755
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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等级
technical
质量水平
方案
≥90% (GC)
包含
silver wool as stabilizer
杂质
~3% methyl cis-4-bromo-2-butenoate
折射率
n20/D 1.501
沸点
70 °C/0.03 mmHg (lit.)
密度
1.498 g/mL at 20 °C (lit.)
官能团
bromo
ester
储存温度
2-8°C
SMILES字符串
COC(=O)\C=C\CBr
InChI
1S/C5H7BrO2/c1-8-5(7)3-2-4-6/h2-3H,4H2,1H3/b3-2+
InChI key
RWIKCBHOVNDESJ-NSCUHMNNSA-N
应用
Methyl trans-4-bromo-2-butenoate (Methyl 4-bromocrotonate) was used in the synthesis of highly substituted benzoxepines or benzopyrans and L-α-amino [4,5-3H]adipic acid.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
197.6 °F
闪点(°C)
92 °C
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
J O'Sullivan et al.
The Biochemical journal, 184(2), 421-426 (1979-11-15)
1. delta-(L-alpha-Amino[4,5-3H]adipyl)-L-cysteinyl-D-[4,4-3H]valine has been synthesized from its constituent amino acids, the L-alpha-amino[4,5-3H]adipic acid being obtained by reduction with 3H2 of methyl 5-acetamido-5,5-diethoxycarbonylpent-2-enoate and subsequent decarboxylation and hydrolysis. 2. In a cell-free system prepared by lysis of protoplasts of Cephalosporium acremonium
An Allylpalladium (IV) Intermediate in the Synthesis of Highly Substituted Benzoxepines and Benzopyrans via Reactions of Stable Pallada (II) cycles with Allyl Bromides.
Guo R, et al.
Organometallics, 26(15), 3784-3783 (2007)
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