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质量水平
检测方案
≥98%
形式
liquid
折射率
n20/D 1.326 (lit.)
bp
94-99 °C (lit.)
密度
1.45 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
COS(=O)(=O)C(F)(F)F
InChI
1S/C2H3F3O3S/c1-8-9(6,7)2(3,4)5/h1H3
InChI key
OIRDBPQYVWXNSJ-UHFFFAOYSA-N
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一般描述
三氟甲磺酸甲酯是一种强甲基化试剂,常用于在温和碱性条件下预甲基化多糖。
应用
三氟甲磺酸甲酯可用作以下应用的甲基化试剂:
- 在使用基于色谱的技术测定富含硫化物的水井中的零价硫,以及锂硫电池中电解质中的多硫化物种类。
- 与烯醇钾反应。
- 将胺转化为三氟甲磺酸铵。
警示用语:
Danger
危险分类
Acute Tox. 1 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
非剧毒-急性毒性1
Ring Expansions of 2-Alkenylazetidinium Salts-a New Route to Pyrrolidines and Azepanes
European Journal of Organic Chemistry, 2006(18), 4214-4223 (2006)
Quantitative and Qualitative Determination of Polysulfide Species in the Electrolyte of a Lithium?Sulfur Battery using HPLC ESI/MS with One?Step Derivatization
Advanced Energy Materials, 5(16) (2015)
Inorganic chemistry, 45(20), 7997-7999 (2006-09-27)
Two cationic carbene complexes with no heteroatom in the ring containing the carbene carbon, trans-bromo(2-methyl-2,6-dihydroisoquinolin-6-ylidene)bis(triphenylphosphine)palladium(II) triflate (3) and trans-chloro(1,2-dimethyl-1,7-dihydroquinolin-7-ylidene)bis(triphenylphosphine)palladium(II) triflate (4), were synthesized by oxidative substitution of Pd(PPh3)4 with N-methylated 6-bromoisoquinolinium and 7-chloro-2-methylquinolinium cations, respectively. Compound 3 was also prepared
Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 57(4), 505-507 (2002-10-04)
This paper describes an improved preparation of [11C]verapamil by reaction of [11C]methyl triflate with desmethylverapamil. The optimal reaction temperature, amount of precursor and reaction time were assessed. With this method [11C]verapamil can be prepared with a reproducible radiochemical yield of
Nuclear medicine and biology, 23(8), 981-986 (1996-11-01)
The important radiotracer precursor 2 beta-carbomethoxy-3 beta-(4-idophenyl)-tropane (beta-CIT, RTI-55) was made in 52% overall yield from cocaine. Key steps were improved conjugate Grignard addition to anhydroecgonine methyl ester with > 3.5:1 2 beta: 2 alpha-isomer selectivity, and a mild new
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