推荐产品
等级
technical grade
质量水平
方案
90%
表单
liquid
折射率
n20/D 1.466 (lit.)
密度
1.152 g/mL at 25 °C (lit.)
官能团
phosphoramide
SMILES字符串
CN(C)P(Cl)(=O)N(C)C
InChI
1S/C4H12ClN2OP/c1-6(2)9(5,8)7(3)4/h1-4H3
InChI key
WYLQARGYFXBZMD-UHFFFAOYSA-N
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应用
N,N,N′,N′-Tetramethylphosphorodiamidic chloride was used in the synthesis of (-)-allohedycaryol and C2-symmetric binaphthyl phosphortriamide. It was also used in total synthesis of neohedycaryol.
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
Total Synthesis of Neohedycaryol. Its Possible Role in the Biosynthesis of Eudesmane Sesquiterpenes.
Adriaan J. Minnaard et al.
The Journal of organic chemistry, 62(8), 2344-2349 (1997-04-18)
The total synthesis of neohedycaryol (4), the C(9)-C(10) double bond regioisomer of the germacrane sesquiterpene hedycaryol, was accomplished in 10 steps from the known dione 6. A Marshall fragmentation of the intermediate mesylate 14 was used to prepare the trans,trans-cyclodeca-1,6-diene
Vladimir N. Zhabinskii et al.
The Journal of organic chemistry, 61(12), 4022-4027 (1996-06-14)
The enantiomer of (+)-allohedycaryol, a germacrane alcohol isolated from giant fennel (Ferula communis L.), has been synthesized, thereby elucidating the relative and absolute stereochemistry of the natural product. The synthesis of (-)-allohedycaryol started from (+)-alpha-cyperone (5) which was available in
A I Meyers et al.
Chirality, 9(5-6), 431-434 (1997-01-01)
By use of an asymmetric Ullmann coupling involving chiral naphthalene oxazolines 1, the title compounds were prepared in good yields and with high diastereoselectivity. Hydrolysis of the binaphthyl oxazolines 2 led to the di-aldehydes 5, which were transformed into the
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