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质量水平
方案
97%
折射率
n20/D 1.453 (lit.)
沸点
168 °C (lit.)
溶解性
alcohol: miscible(lit.)
diethyl ether: miscible(lit.)
water: insoluble(lit.)
密度
1.378 g/mL at 25 °C (lit.)
SMILES字符串
CCOC(=O)C(Cl)(Cl)Cl
InChI
1S/C4H5Cl3O2/c1-2-9-3(8)4(5,6)7/h2H2,1H3
InChI key
SJMLNDPIJZBEKY-UHFFFAOYSA-N
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一般描述
Ethyl trichloroacetate undergoes atom-transfer radical addition reaction with styrene catalyzed by the Ru-pentamethylcyclopentadienyl complexes.
应用
Ethyl trichloroacetate was used in the synthesis of dichlorocarbon precursor, phenyl(trichloromethyl)methyl.
警示用语：
Warning
危险声明
危险分类
Acute Tox. 4 Oral - Skin Irrit. 2
储存分类代码
10 - Combustible liquids
WGK
WGK 1
闪点(°F)
163.4 °F - closed cup
闪点(°C)
73 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Mariano A Fernández-Zúmel et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 15(43), 11601-11607 (2009-09-15)
Kinetic and spectroscopic analyses were performed to gain information about the mechanism of atom-transfer radical reactions catalyzed by the complexes [RuCl2Cp*(PPh3)] and [RuClCp*(PPh3)2] (Cp*=pentamethylcyclopentadienyl), in the presence and in the absence of the reducing agent magnesium. The reactions of styrene
An Improved Synthesis of Phenyl (trichloro-methyl) mercury from Sodium Methoxide and Ethyl Trichloroacetate.
Schweizer EE and O'Neill GJ.
The Journal of Organic Chemistry, 28(3), 851-852 (1963)
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