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Merck
CN

163015

Sigma-Aldrich

硝酸铊(III) 三水合物

别名:

TTN, 三硝酸铊

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About This Item

线性分子式:
Tl(NO3)3 · 3H2O
CAS号:
分子量:
444.44
EC 号:
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22

质量水平

反应适用性

core: thallium
reagent type: catalyst

mp

102-105 °C (lit.)

SMILES字符串

O.O.O.[Tl+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/3NO3.3H2O.Tl/c3*2-1(3)4;;;;/h;;;3*1H2;/q3*-1;;;;+3

InChI key

ZCPIKMRXMBJLCP-UHFFFAOYSA-N

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应用

本试剂可用于将苯乙烯衍生物快速氧化成羰基化合物,用于通过氧化重排进行环芳烷基酮的区域选择性扩环反应,用于硫缩醛到羰基化合物的选择性水解以及用于 19-降甾族化合物的一般合成方法。介导环酮的缩环反应,生成一系列反式稠合的 10-甲基-2-萘烷酮。

警示用语:

Danger

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

危险化学品
铊类化学品

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Journal of the American Chemical Society, 98, 3037-3037 (1976)
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To understand the characteristics of ADSSL1 myopathy, we investigated the clinical manifestation in Korean patients with ADSSL1 mutations. We developed a targeted panel of 16 distal-myopathy genes and recruited a total of 12 patients with genetically undetermined distal myopathy. We
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The Journal of molecular diagnostics : JMD, 20(4), 465-473 (2018-04-25)
Interpretation of next-generation sequencing constitutes the main limitation of molecular diagnostics. In diagnosing myopathies and muscular dystrophies, another issue is efficiency in predicting the pathogenicity of variants identified in large genes, especially TTN; current in silico prediction tools show limitations

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Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis

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