推荐产品
蒸汽压
1.4 mmHg ( 20 °C)
质量水平
方案
99%
表单
liquid
expl. lim.
16.3 %
折射率
n20/D 1.443 (lit.)
沸点
140 °C (lit.)
密度
0.848 g/mL at 25 °C (lit.)
官能团
hydroxyl
SMILES字符串
C\C(C)=C\CO
InChI
1S/C5H10O/c1-5(2)3-4-6/h3,6H,4H2,1-2H3
InChI key
ASUAYTHWZCLXAN-UHFFFAOYSA-N
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一般描述
3-甲基-2-丁烯-1-醇可与亚硝基羰基苯反应生成5-羟基-异恶唑烷。它常被用作芳香成分。
应用
在通过Sharpless不对称环氧化反应不对称全合成(R)-(+)-和(S)-(-)-羟甲基甲基呋喃酮时，3-甲基-2-丁烯-1-醇被用作起始试剂。
警示用语：
Danger
危险分类
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
124.7 °F - closed cup
闪点(°C)
51.5 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Anastasia Zerva et al.
Molecules (Basel, Switzerland), 23(9) (2018-09-22)
Feruloyl esterases (FAEs, E.C. 3.1.1.73) are biotechnologically important enzymes with several applications in ferulic acid production from biomass, but also in synthesis of hydroxycinnamic acid derivatives. The use of such biocatalysts in commercial processes can become feasible by their immobilization
Hong Liang et al.
Metabolic engineering, 65, 223-231 (2020-11-29)
Engineering microbes to utilize non-conventional substrates could create short and efficient pathways to convert substrate into product. In this study, we designed and constructed a two-step heterologous ethanol utilization pathway (EUP) in Escherichia coli by using acetaldehyde dehydrogenase (encoded by
Takeshi Bamba et al.
Journal of separation science, 32(15-16), 2699-2706 (2009-07-17)
Monolithic silica columns have very low back-pressures and offer several advantages over conventional columns packed with spherical particles, such as high separation efficiency and rapid analysis. In this review, we report the applicability of monolithic silica columns for the analysis
Vijay Gnanadesikan et al.
Journal of the American Chemical Society, 130(25), 8089-8093 (2008-05-23)
An effective strategy has been developed for the efficient site-selective epoxidation of poylolefinic isoprenoid alcohols, based on the use of an internal control element for intramolecular reaction. The approach is illustrated by application to a series of polyisoprenoid alcohols (polyprenols)
Branko Radetich et al.
Journal of the American Chemical Society, 124(11), 2430-2431 (2002-03-14)
A solution is reported to the classic unsolved problem of stereoselective synthesis of all-E oligoprenols, such as E-farnesylfarnesol, by a cationic coupling analogous to the biosynthetic pathway. The simplicity and efficacy of the method, which is outlined in Scheme 1
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