161756
溴甲基甲基醚
technical grade, 90%
别名:
1-溴甲基甲醚, 溴甲基甲基醚, 甲氧基甲基溴
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线性分子式:
BrCH2OCH3
化学文摘社编号:
分子量:
124.96
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
产品名称
溴甲基甲基醚, technical grade, 90%
InChI
1S/C2H5BrO/c1-4-2-3/h2H2,1H3
SMILES string
COCBr
InChI key
JAMFGQBENKSWOF-UHFFFAOYSA-N
grade
technical grade
assay
90%
form
liquid
refractive index
n20/D 1.456 (lit.)
bp
87 °C (lit.)
density
1.531 g/mL at 25 °C (lit.)
functional group
bromo
ether
storage temp.
2-8°C
Quality Level
Application
溴甲基甲基醚已被用于含有大环免疫抑制剂FK-506的碳18至35中间体的对映体控制合成。它已被用于合成1-甲氧基甲基-4-三苯甲硫基-2-氮杂环丁酮。
signalword
Warning
Hazard Classifications
Acute Tox. 4 Dermal - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
80.6 °F - closed cup
flash_point_c
27 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Nuclear analogs of β-lactam antibiotics. XVI. Aldol condensations of N-protected 4-tritylthio-2-azetidinones.
Martel A, et al.
Canadian Journal of Chemistry, 61(3), 613-618 (1983)
Enantioselective synthesis of the C (18)-C (35) segment of immunosuppressant FK-506 using efficient new methodology.
Corey EJ and Huang H-C.
Tetrahedron Letters, 30(39), 5235-5238 (1989)
Archana Prasad et al.
Scientific reports, 6, 39490-39490 (2016-12-22)
Amyotrophic lateral sclerosis (ALS) is a fatal neurodegenerative disease associated with aggregation of TAR DNA-binding protein-43 (TDP-43) in neuronal cells and manifests as motor neuron dysfunction &muscle atrophy. The carboxyl-terminal prion-like domain of TDP-43 can aggregate in vitro into toxic
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