161195
2-甲氧基-5-硝基苯胺
98%
别名:
5-硝基邻茴香胺
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线性分子式:
CH3OC6H3(NO2)NH2
化学文摘社编号:
分子量:
168.15
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
202-770-5
MDL number:
Assay:
98%
InChI key
NIPDVSLAMPAWTP-UHFFFAOYSA-N
InChI
1S/C7H8N2O3/c1-12-7-3-2-5(9(10)11)4-6(7)8/h2-4H,8H2,1H3
SMILES string
COc1ccc(cc1N)[N+]([O-])=O
assay
98%
mp
117-119 °C (lit.)
General description
2-Methoxy-5-nitroaniline is an aromatic metabolite of 2,4-dinitroanisole.
Application
2-Methoxy-5-nitroaniline was used in the synthesis of 5-(9-acridinylamino)-p-anisidines via reaction with 9-anilinoacridines. It was also used in the synthesis of disazo disperse dyes containing nitro and methoxy groups, used for the dyeing of polyester fibre.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral
存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
246.2 °F - closed cup
flash_point_c
119 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
Disperse dyes derived from 2-methoxy-5-nitroaniline.
Otutu JO and Osabohien E.
Orient. J. Chem., 25(4), 863-863 (2009)
A Dewanji et al.
Biometrics, 49(2), 367-377 (1993-06-01)
In this paper, a new method of estimating tumorigenic potency is proposed that takes into account information on survival and, when available, the underlying cause of death. Specifically, Weibull distributions are used to describe the time to tumor occurrence (X)
Valeriy A Bacherikov et al.
Bioorganic & medicinal chemistry, 13(23), 6513-6520 (2005-09-06)
A series of 5-(9-acridinylamino)anisidines were synthesized by condensing methoxy-substituted 1,3-phenylenediamines (10 and 11) with 9-chloroacridine derivatives to form 5-(9-acridinylamino)-m-anisidines (AMAs, 14a-e) and 5-(9-acridinylamino)-o-anisidines (AOAs, 15a-e). 5-(9-Acridinylamino)-p-anisidines (APAs, 17a-e) were synthesized by reacting 2-methoxy-5-nitroaniline (12) with 9-anilinoacridines, followed by reduction. The
5-Nitro-ortho-anisidine.
IARC monographs on the evaluation of the carcinogenic risk of chemicals to humans, 27, 133-139 (1982-04-01)
Raju Khatiwada et al.
Chemosphere, 201, 790-798 (2018-03-20)
Abiotic transformation of anthropogenic compounds by redox-active metal oxides affects contaminant fate in soil. The capacity of birnessite and ferrihydrite to oxidize the insensitive munitions compound, 2,4-dinitroanisol (DNAN), and its amine-containing daughter products, 2-methoxy-5-nitro aniline (MENA) and 2,4-diaminoanisole (DAAN), was
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