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160938

Sigma-Aldrich

Resolve-Al EuFOD

99%

别名:

Eu(fod)3, Sievers 试剂, 三(1,1,1,2,2,3,3-七氟-7,7-二甲基-4,6-辛二酮酸)铕(III), 三(6,6,7,7,8,8,8-七氟-2,2-二甲基-3,5-辛二酮酸)铕

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About This Item

线性分子式:
Eu(OCC(CH3)3CHCOCF2CF2CF3)3
CAS号:
17631-68-4
分子量:
1037.49
EC 号:
241-616-1
MDL编号:
MFCD00064655
UNSPSC代码:
12161600
PubChem化学物质编号:
24849895
NACRES:
NA.22

方案

99%

表单

solid

反应适用性

core: erbium
reagent type: catalyst

mp

203-207 °C

SMILES字符串

CC(C)(C)C(\O[Eu](O\C(=C/C(=O)C(F)(F)C(F)(F)C(F)(F)F)C(C)(C)C)O\C(=C/C(=O)C(F)(F)C(F)(F)C(F)(F)F)C(C)(C)C)=C\C(=O)C(F)(F)C(F)(F)C(F)(F)F

InChI

1S/3C10H11F7O2.Eu/c3*1-7(2,3)5(18)4-6(19)8(11,12)9(13,14)10(15,16)17;/h3*4,18H,1-3H3;/q;;;+3/p-3/b3*5-4-;

InChI key

PTQJQBFRLLGICD-VNGPFPIXSA-K

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相关类别

一般描述

在氧代琥珀酸盐衍生物的自由基介导烯丙基化反应中增强立体选择性。

应用

当与 Resolve-Al AgFOD 结合使用时，可为芳香族化合物、铵盐以及锍和异硫脲卤化物提供有效的 NMR 位移试剂。

法律信息

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
0000221940
0000221940
0000209682
0000209681
0000151485

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The Journal of Organic Chemistry, 50, 1322-1322 (1985)
Journal of the American Chemical Society, 102, 5903-5903 (1980)
A B Ellis et al.
Proceedings of the National Academy of Sciences of the United States of America, 78(7), 3993-3997 (1981-07-01)
Several retinal isomers are shown to form adducts in isooctane solution with a lanthanide beta-diketonate complex, tris(6,6,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)europium(III) [Eu(fod)3]. The adducts are characterized by an absorption band whose lambda max at approximately 420 nm is red-shifted by approximately 60 nm from
J P Caldwell et al.
Journal of forensic sciences, 46(6), 1332-1341 (2001-11-21)
The utilization of the lanthanide shift reagent tris (6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato) europium (III) [Eu(fod)3] as a simple one-step reagent for the luminescent visualization of latent fingerprints has been investigated. UV excitation of Eu(fod)3-treated prints, achieved by using a hand-held UV lamp or
Michiya Fujiki et al.
Frontiers in chemistry, 8, 685-685 (2020-09-10)
We report emerging circularly polarized luminescence (CPL) at 4f-4f transitions when lanthanide (EuIII and TbIII) tris(β-diketonate) embedded to cellulose triacetate (CTA), cellulose acetate butyrate (CABu), D-/L-glucose pentamethyl esters ( D-/ L-Glu), and D-/L-arabinose tetramethyl esters ( D-/ L-Ara) are in
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