160938
Resolve-Al EuFOD
99%, solid
别名:
Eu(fod)3, Sievers 试剂, 三(1,1,1,2,2,3,3-七氟-7,7-二甲基-4,6-辛二酮酸)铕(III), 三(6,6,7,7,8,8,8-七氟-2,2-二甲基-3,5-辛二酮酸)铕
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选择尺寸
关于此项目
线性分子式:
Eu(OCC(CH3)3CHCOCF2CF2CF3)3
化学文摘社编号:
分子量:
1037.49
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
241-616-1
MDL number:
产品名称
Resolve-Al EuFOD, 99%
InChI key
PTQJQBFRLLGICD-VNGPFPIXSA-K
InChI
1S/3C10H11F7O2.Eu/c3*1-7(2,3)5(18)4-6(19)8(11,12)9(13,14)10(15,16)17;/h3*4,18H,1-3H3;/q;;;+3/p-3/b3*5-4-;
SMILES string
CC(C)(C)C(\O[Eu](O\C(=C/C(=O)C(F)(F)C(F)(F)C(F)(F)F)C(C)(C)C)O\C(=C/C(=O)C(F)(F)C(F)(F)C(F)(F)F)C(C)(C)C)=C\C(=O)C(F)(F)C(F)(F)C(F)(F)F
assay
99%
form
solid
reaction suitability
core: erbium
reagent type: catalyst
mp
203-207 °C
Quality Level
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Application
当与 Resolve-Al AgFOD 结合使用时，可为芳香族化合物、铵盐以及锍和异硫脲卤化物提供有效的 NMR 位移试剂。
General description
在氧代琥珀酸盐衍生物的自由基介导烯丙基化反应中增强立体选择性。
Legal Information
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Journal of the American Chemical Society, 102, 5903-5903 (1980)
The Journal of Organic Chemistry, 50, 1322-1322 (1985)
K D Schulze et al.
Biochimica et biophysica acta, 1467(1), 27-38 (2000-08-10)
Investigating the action of the fluorinated europium complex Eu(fod)3 on lipid membranes we found that the complex facilitates the ion transfer through the membrane. Electric measurements on planar lipid membranes showed that the membrane conductivity increases considerably by insertion of
A B Ellis et al.
Proceedings of the National Academy of Sciences of the United States of America, 78(7), 3993-3997 (1981-07-01)
Several retinal isomers are shown to form adducts in isooctane solution with a lanthanide beta-diketonate complex, tris(6,6,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)europium(III) [Eu(fod)3]. The adducts are characterized by an absorption band whose lambda max at approximately 420 nm is red-shifted by approximately 60 nm from
Analytical Chemistry, 59, 562-562 (1987)
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