160385
酞酰亚胺 钾盐
98%
别名:
邻苯二甲酰亚胺 钾盐, 酞酰亚胺钾
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关于此项目
经验公式（希尔记法）:
C8H4KNO2
化学文摘社编号:
分子量:
185.22
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
214-046-6
Beilstein/REAXYS Number:
3598719
MDL number:
Assay:
98%
Form:
powder
InChI key
FYRHIOVKTDQVFC-UHFFFAOYSA-M
InChI
1S/C8H5NO2.K/c10-7-5-3-1-2-4-6(5)8(11)9-7;/h1-4H,(H,9,10,11);/q;+1/p-1
SMILES string
[K]N1C(=O)c2ccccc2C1=O
assay
98%
form
powder
mp
>300 °C (lit.)
solubility
water: soluble 50 mg/mL, clear to slightly hazy, colorless to yellow
functional group
imide
Quality Level
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Application
邻苯二甲酰亚胺钾盐被用作一种有机催化剂，用于在极其温和的条件下对各种羰基化合物进行氰基甲硅烷基化。它还被用于将烯丙基-和烷基卤化物转化为受保护的伯胺。
酞酰亚胺钾与有机卤化物在二甲基甲酰胺中的缩合反应已有报告。邻苯二酰亚胺钾与一氯化硫在石油醚中的反应已被研究。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
346.3 °F - closed cup
flash_point_c
174.6 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
An improved procedure for the condensation of potassium phthalimide with organic halides.
Sheehan JC and Bolhofer WA.
Journal of the American Chemical Society, 72(6), 2786-2788 (1950)
Reactions of Phthalimide and Potassium Phthalimide with Sulfur Monochloride.
Kalnins MV.
Canadian Journal of Chemistry, 44(17), 2111-2113 (1966)
Activation of trimethylsilyl cyanide by potassium phthalimide for facile synthesis of TMS-protected cyanohydrins.
Dekamin MG and Karimi Z.
Journal of Organometallic Chemistry, 694(12), 1789-1794 (2009)
Palladium-catalyzed direct functionalization of imidazolinone: synthesis of dibromophakellstatin.
Jianming Lu et al.
Journal of the American Chemical Society, 129(25), 7768-7769 (2007-06-02)
Tetrahedron Letters, 48, 3043-3043 (2007)
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